Synthesis of [Sb2W20Fe2II(H2O)(6)O-70](10-) with iron powder under mild conditions and its applications in both catalytic Fenton reaction and electrochemical sensing of ascorbic acid

Sun Minghui; Li Fengyan; Yu Longjiao; Wang Ya; Xu Lin

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Synthesis of [Sb2W20Fe2II(H2O)(6)O-70](10-) with iron powder under mild conditions and its applications in both catalytic Fenton reaction and electrochemical sensing of ascorbic acid

机译：铁粉在温和条件下合成[Sb2W20Fe2II（H2O）（6）O-70]（10-）及其在催化芬顿反应和抗坏血酸电化学检测中的应用

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The first Krebs-type tungstoantimonate containing ferrous ions Na2H4[C3H5N2](4)[Sb2W20Fe2II(H2O)(6)O-70]center dot 12H(2)O (1) was prepared by a new route of synthesis under mild reaction conditions. The facile synthesis route represented a favourable tactic for the successful synthesis of FeII-based polyoxometalate. Its applications in both catalytic Fenton reaction and electrochemical sensing of ascorbic acid were also investigated primarily.

机译：通过在温和的反应条件下通过新的合成路线制备了第一个包含亚铁离子Na2H4 [C3H5N2]（4）[Sb2W20Fe2II（H2O）（6）O-70]中心点12H（2）O（1）的Krebs型钨酸锑酸盐。简便的合成路线是成功合成基于FeII的多金属氧酸盐的有利策略。还初步研究了其在催化Fenton反应和抗坏血酸电化学检测中的应用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第6期|共5页
作者
Sun Minghui; Li Fengyan; Yu Longjiao; Wang Ya; Xu Lin;
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1. Synthesis of [Sb2W20Fe2II(H2O)(6)O-70](10-) with iron powder under mild conditions and its applications in both catalytic Fenton reaction and electrochemical sensing of ascorbic acid [J] . Sun Minghui, Li Fengyan, Yu Longjiao, Dalton transactions: An international journal of inorganic chemistry . 2016,第6期

机译：铁粉在温和条件下合成[Sb2W20Fe2II（H2O）（6）O-70]（10-）及其在催化芬顿反应和抗坏血酸电化学检测中的应用
2. Nanoflakes of an aminoacid-based chiral coordination polymer: Synthesis, optical and electrochemical properties, and application in electrochemical sensing of H2O2 [J] . Zhou Bo, Liang Li-Mei, Yao Jie Journal of Solid State Chemistry . 2015,第Null期

机译：氨基酸基手性配位聚合物的纳米薄片：H2O2的合成，光学和电化学性质及其在电化学传感中的应用
3. MoS2 QDs co-catalytic Fenton reaction for highly sensitive photoluminescence sensing of H2O2 and glucose [J] . Tianli Wang, Xue Hu, Xiaodan Zhang, Analytical methods . 2019,第4期

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5. RuCl3·3H2O Catalyzed Reactions: Facile Synthesis of Bis(indolyl)methanes under Mild Conditions [O] . Hong-En Qu, Chen Xiao, Ning Wang, 2011

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6. Catalytic degradation of Acid Orange 7 by H2O2 as promoted by either bare or V-loaded titania under UV light, in dark conditions, and after incubating the catalysts in ascorbic acid [O] . Piumetti, Marco, Freyria, Francesca Stefania, Armandi, Marco, 2015

机译：在紫外光下，在黑暗条件下以及在抗坏血酸中孵育催化剂后，通过裸露或负载V的二氧化钛促进H2O2催化降解酸性橙7

Synthesis of [Sb2W20Fe2II(H2O)(6)O-70](10-) with iron powder under mild conditions and its applications in both catalytic Fenton reaction and electrochemical sensing of ascorbic acid

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