Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

Voelcker Franziska; Roesky Peter W.

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Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

机译：膦酰胺连接的双金属稀土/铂配合物

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The heterometallic early-late 5d/4f binuclear phosphinoamido Ln/Pt(0) complexes [(Ph2PNHPh) Pt(mu-(Ph2PNPh)}(3)Ln(mu-Cl)Li(THF)(3)] (Ln = Y (1a), Lu (1b)) were obtained by reaction of [Li(THF)(4)] [(Ph2PNPh)(4)Ln] (Ln = Y, Lu) with the Pt(0) complex [Pt(tBu(3)P)(2)] in the presence of LiCt. In the absence of LiCl the corresponding Ln/Pt(0) complexes [(Ph2PNHPh)Pt{mu-(Ph2PNPh)}(3)Ln{eta(2)-(Ph2PNPW[Li(THF)(4)] (Ln = Y (2a), Lu (2b)) were isolated. Both kind of complexes decompose in solution. The Pt(0) complex [Pt(Ph2PNHPh)(4)] (3) was identified as one of these decomposition products.

机译：杂金属早期5d / 4f双核膦酰氨基Ln / Pt（0）络合物[（Ph2PNHPh）Pt（mu-（Ph2PNPh）}（3）Ln（mu-Cl）Li（THF）（3）]（Ln = Y （1a），Lu（1b））是通过[Li（THF）（4）] [（Ph2PNPh）（4）Ln]（Ln = Y，Lu）与Pt（0）络合物[Pt（tBu）（3）P）（2）]在LiCt存在下，在LiCl不存在时，相应的Ln / Pt（0）络合物[（Ph2PNHPh）Pt {mu-（Ph2PNPh）}（3）Ln {eta（2） -（Ph2PNPW [Li（THF）（4）]（Ln = Y（2a），Lu（2b））分离。两种络合物均在溶液中分解。Pt（0）络合物[Pt（Ph2PNHPh）（4） ]（3）被确定为这些分解产物之一。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第23期|共7页
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Voelcker Franziska; Roesky Peter W.;
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1. Bimetallic rare-earth/platinum complexes ligated by phosphinoamides [J] . Voelcker Franziska, Roesky Peter W. Dalton transactions: An international journal of inorganic chemistry . 2016,第23期

机译：膦酰胺连接的双金属稀土/铂配合物
2. Bimetallic rare-earth/platinum complexes ligated by phosphinoamides [J] . Voelcker Franziska, Roesky Peter W. Dalton transactions: An international journal of inorganic chemistry . 2016,第23期

机译：膦酰胺连接的双金属稀土/铂配合物
3. Bimetallic Arylamide-Ligated Rare-Earth Metal Complexes: Synthesis, Characterization, and Stereo-Selectively Switchable Property in 2-Vinylpyridine Polymerization [J] . Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第5期

机译：双金属芳基酰胺连接的稀土金属配合物：2-乙烯基吡啶聚合中的合成，表征和立体选择性可切换性质
4. Preparation and Properties of Chelate Complexes of Tungsten(O)and Platinum(II) Ligated by Bulky 3-Thioxo-l,3-diphosphapropenes [C] . Shigekazu Ito, Hongze Liang, Masaaki Yoshifuji Symposium on Organometallic Chemistry . 2003

机译：铜酸盐配合物的制备与甘氨酸（II）通过庞大的3-硫代氧-1，3-二磷丙酮连接的铂（II）
5. Bond activation by nitrogen ligated platinum(II)/platinum(IV) complexes. [D] . West, Nathan M. 2008

机译：通过氮连接的铂（II）/铂（IV）络合物的键活化。
6. Cis-14-Polymerization of Isoprene by 13-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes [O] . Chao Yu, Dahai Zhou, Xiangqian Yan, 2017

机译：13-双（恶唑啉基亚甲基）异吲哚啉连接的稀土金属二烷基配合物的异戊二烯的Cis-14-聚合
7. Bimetallic rare-earth/platinum complexes ligated by phosphinoamides [O] . Franziska Völcker, Peter W. Roesky 2016

机译：双金属稀土/铂复合物通过磷基酰胺连接
8. Early-Late Heterobimetallic Complexes Linked By Phosphinoamide Ligands. Tuning Redox Potentials and Small Molecule Activation. [R] . Thomas, C. M. 2015

机译：由膦酰胺配体连接的早期晚期异双金属配合物。调整氧化还原电位和小分子激活。

Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

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