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Chemical modification process of an atactic polypropylene by p-phenylen-bismaleamic acid in the melt

机译:对亚苯基双马来酰胺酸熔体对无规聚丙烯的化学改性方法

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This study was concerned with the chemical modification process of an atactic polypropylene from polymerization reactor byproducts with p-phenylen-bismaleamic acid to obtain a new grafted polymer supposed to play an important role as an interfacial agent in heterogeneous systems based on polymers. The grafting process was undertaken with the aid of the Box-Wilson experimental worksheet, with two independent variables (or controlled factors), the level of polar monomer to be grafted in the polymer and the concentration of the initiator, and with the agitation rate kept constant. Each item of the experimental design was performed at four different reaction times. This latter let us ascertain the transient nature of the process and the existence of a critical point in the concentration of both reactants conducting the system to the maximum grafting yield. (C) 2003 Wiley Periodicals, Inc. [References: 40]
机译:这项研究与聚合反应器副产物与对亚苯基双马来酰胺酸对无规立构聚丙烯的化学改性过程有关,以获得一种新的接枝聚合物,该聚合物在基于聚合物的多相体系中作为界面剂起着重要作用。接枝过程是在Box-Wilson实验工作表的帮助下进行的,具有两个独立变量(或受控因素),即聚合物中接枝的极性单体的含量和引发剂的浓度,并保持搅拌速率不变。实验设计的每个项目均在四个不同的反应时间进行。后者使我们确定了过程的瞬时性质,以及使体系达到最大接枝产率的两种反应物的浓度中存在临界点。 (C)2003 Wiley Periodicals,Inc. [参考:40]

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