Evaluation of the diethylene glycol bis(allyl carbonate)/acrylic acid copolymer behavior by solid-state C-13-NMR

da Silva EP; Tavares MIB; Fraga LA; Kaplan MAC

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Evaluation of the diethylene glycol bis(allyl carbonate)/acrylic acid copolymer behavior by solid-state C-13-NMR

机译：通过固态C-13-NMR评估二甘醇双（碳酸烯丙酯）/丙烯酸共聚物的行为

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The dynamic behavior of diethylene glycol bis(allyl carbonate) (CR-39)/acrylic acid (AA) copolymers was evaluated by C-13 high-resolution solid-state nuclear magnetic resonance (NMR). The NMR data showed that the copolymerization of CR-39 and AA generated copolymers with different molecular behaviors as a function of AA content, which promoted changes in the crosslinking of CR-39 chains and in the intramolecular forces. The copolymerization process influenced the sequence distribution and domain formation of the monomers, which is a consequence of the dispersion of comonomers along the macromolecular chains. (c) 2005 Wiley Periodicals, Inc.

机译：通过C-13高分辨率固态核磁共振（NMR）评估了二乙二醇双（碳酸烯丙酯）（CR-39）/丙烯酸（AA）共聚物的动力学行为。 NMR数据表明，CR-39和AA的共聚反应产生的分子行为随AA含量的变化而变化，这促进了CR-39链的交联和分子内力的变化。共聚过程影响单体的序列分布和结构域形成，这是共聚单体沿着高分子链分散的结果。（c）2005年Wiley Periodicals，Inc.

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《Journal of Applied Polymer Science》 |2005年第3期|共6页
作者
da Silva EP; Tavares MIB; Fraga LA; Kaplan MAC;
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正文语种 eng
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CR-39; acrylic acid; NMR; copolymerization; crosslinking; NUCLEAR-MAGNETIC-RESONANCE;

机译：CR-39;丙烯酸;NMR;共聚;交联;核磁共振;

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1. Evaluation of the diethylene glycol bis(allyl carbonate)/acrylic acid copolymer behavior by solid-state C-13-NMR [J] . da Silva EP, Tavares MIB, Fraga LA, Journal of Applied Polymer Science . 2005,第3期

机译：通过固态C-13-NMR评估二甘醇双（碳酸烯丙酯）/丙烯酸共聚物的行为
2. Curing of the Diethylene Glycol Bis(Allyl Carbonate) Determination of the Kinetic Triplet 4 Ea,app,f(alpha) Using the Isoconversional Method and Compensation Effect [J] . D.Klinar, J.Golob, M.Krajnc Chemical and Biochemical Engineering Quarterly . 2004,第1期

机译：等乙二醇转化的二乙二醇双碳酸烯丙酯的固化测定动力学三重态4 Ea，app，f（alpha）
3. Curing of the Diethylene Glycol Bis(Allyl Carbonate) Determination of the Kinetic Triplet A, Ea,app, f(α) Using the Isoconversional Method and Compensation Effect [J] . D. Klinar, J. Golob, M. Krajnc Chemical and Biochemical Engineering Quarterly . 2004,第2004期

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4. Study on the Polymerization Kinetics of Methyl Allyl Polyethylene Glycol with Acrylic Acid [C] . Ziming Wang, Yang Zhang, Jingying Peng, International conference on superplasticizers and other chemical admixtures in concrete . 2018

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5. Cytotoxic effects of diglycolic acid, the nephrotoxic metabolite of diethylene glycol, and the mechanisms leading to proximal tubule cell dysfunction. [D] . Landry, Greg Matthew. 2013

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6. Mucoadhesive and Rheological Studies on the Co-Hydrogel Systems of Poly(Ethylene Glycol) Copolymers with Fluoroalkyl and Poly(Acrylic Acid) [O] . Yang Sun, Adiel F. Perez, Ivy L. Cardoza, 2021

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7. Study of the new route for aliphatic carbonates and application to diethylene glycol bis-allyl carbonate production. [O] . Toshiaki SHIGEMUNE, Kazuo SHIKATA 1985

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Evaluation of the diethylene glycol bis(allyl carbonate)/acrylic acid copolymer behavior by solid-state C-13-NMR

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