Controlled/Living RAFT Polymerization of N-Phenyl Maleimide and Synthesis of Its Block Copolymers

Li AL; Lu J

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Controlled/Living RAFT Polymerization of N-Phenyl Maleimide and Synthesis of Its Block Copolymers

机译：N-苯基马来酰亚胺的可控/活性RAFT聚合及其嵌段共聚物的合成

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The controlled/living radical polymerization of N-phenyl maleimide (NPMI) was achieved using 2,2'-azobisisobutyronitrile as the initiator and 2-cyanopropyl-2-yl dithiobenzoate as the reversible addition-fragmentation chain transfer agent at 75 degrees C in dichloroethane/ethylene carbonate (60/40, w/w) mixed solvent. The block copolymers of polystyrene-b-polyNPMI and poly(n-butyl methacrylate)-b-polyNPMI were successfully prepared by chain extension from dithiobenzoate-terminated polystyrene and poly (n-butyl methacrylate) to NPMI, respectively. The obtained NPMI-based (co)polymers were characterized by gel permeation chromatography and H-1-NMR spectroscopy.

机译：使用2,2'-偶氮二异丁腈作为引发剂和2-氰基丙基-2-基二硫代苯甲酸酯作为可逆加成-断裂链转移剂，在二氯乙烷中在75摄氏度下实现N-苯基马来酰亚胺（NPMI）的受控/活性自由基聚合。 /碳酸亚乙酯（60/40，w / w）混合溶剂。通过将二硫代苯甲酸酯封端的聚苯乙烯和聚（甲基丙烯酸正丁酯）扩链，分别成功地制备了聚苯乙烯-b-polyNPMI和聚（甲基丙烯酸正丁酯）-b-polyNPMI的嵌段共聚物。通过凝胶渗透色谱和H-1-NMR光谱对获得的基于NPMI的（共）聚合物进行表征。

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《Journal of Applied Polymer Science》 |2009年第4期|共5页
作者
Li AL; Lu J;
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正文语种 eng
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N-phenyl maleimide; RAFT polymerization; block copolymer; heat-resistant polymer;

机译：N-苯基马来酰亚胺;RAFT聚合;嵌段共聚物;耐热性聚合物;

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专利

1. Controlled/Living RAFT Polymerization of N-Phenyl Maleimide and Synthesis of Its Block Copolymers [J] . Li AL, Lu J Journal of Applied Polymer Science . 2009,第4期

机译：N-苯基马来酰亚胺的可控/活性RAFT聚合及其嵌段共聚物的合成
2. Synthesis of thermoresponsive block and graft copolymers via the combination of living cationic polymerization and RAFT polymerization using a vinyl ether-type RAFT agent [J] . Akmal Hadi MaRadzi, Shinji Sugihara, Soichiro Miura, Polymer: The International Journal for the Science and Technology of Polymers . 2014,第8期

机译：使用乙烯基醚型RAFT试剂通过活性阳离子聚合和RAFT聚合相结合来合成热敏性嵌段和接枝共聚物
3. Synthesis of dual thermoresponsive ABA triblock copolymers by both living cationic vinyl polymerization and RAFT polymerization using a dicarboxylic RAFT agent [J] . Sugihara S., Iwata K., Miura S., Polymer: The International Journal for the Science and Technology of Polymers . 2013,第3期

机译：使用二羧酸RAFT剂通过活性阳离子乙烯基聚合和RAFT聚合合成双热响应性ABA三嵌段共聚物
4. SYNTHESIS OF WELL-DEFINED STAR AND BLOCK COPOLYMERS BY LIVING/CONTROLLED POLYMERIZATION [C] . Youliang Zhao, Qiang Liu, Chengbo Zhang, International symposium on polymer chemistry : Preprints. . 2010

机译：生命/控制聚合合成定义明确的星型和嵌段共聚物
5. Controlled/living polymerizations. A. Synthesis of block copolymers with bicyclic acetals by cationic ring opening polymerization. B. Synthesis and study of tetradentate ligands coordinated to copper(I) and copper(II) for use as ATRP catalysts. [D] . Troeltzsch, Christina. 2003

机译：受控/活性聚合。 A.通过阳离子开环聚合反应与双环缩醛合成嵌段共聚物。 B.用作ATRP催化剂的与铜（I）和铜（II）配位的四齿配体的合成和研究。
6. Dually responsive multiblock copolymers via RAFT polymerization: Synthesis of temperature- and redox-responsive copolymers of PNIPAM and PDMAEMA [O] . Ye-Zi You, Qing-Hui Zhou, Devika Soundara Manickam, -1

机译：通过RAFT聚合的双响应多嵌段共聚物：PNIPAM和PDMAEMA的温度响应和氧化还原响应共聚物的合成
7. Synthesis of Poly(vinyl alcohol) Graft Copolymers by Living Cationic Polymerization in the Presence of Added Bases I. Design and Synthesis of Poly(vinyl alcohol) Graft Copolymers with Well-Controlled Poly(vinyl ether) Grafts [O] . Sadahito Aoshima, Masakuni Ikeda, Koji Nakayama, 2001

机译：在添加的碱基I中存在阳离子聚合来合成聚（乙烯醇）接枝共聚物。用良好控制的聚（乙烯基醚）移植物的聚（乙烯醇）接枝共聚物的设计和合成聚（乙烯醇）接枝共聚物
8. Synthesis of Side Chain Liquid Crystal Polymers by Living Ring Opening Metathesis Polymerization. 4. Synthesis of Amorphous and Side Chain Liquid Crystal AB Block Copolymers. [R] . Komiya, Z., Pugh, C., Schrock, R. R. 1992

机译：活环开环易位聚合法合成侧链液晶聚合物。 4.非晶和侧链液晶aB嵌段共聚物的合成。

Controlled/Living RAFT Polymerization of N-Phenyl Maleimide and Synthesis of Its Block Copolymers

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