Effect of Crystallinity on Surface Morphology and Light Transmittance of Poly(vinylidene fluoride-co-hexafluoropropylene) Thin Film

Lee SG; Lee JS; Ha JW; Park IJ; Lee SB; Lee JD

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Effect of Crystallinity on Surface Morphology and Light Transmittance of Poly(vinylidene fluoride-co-hexafluoropropylene) Thin Film

机译：结晶度对聚偏二氟乙烯-共-六氟丙烯薄膜的表面形貌和透光率的影响

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Homopolymer of vinylidene fluoride and its copolymers containing hexafluoropropylene (HFP) were prepared from free radical solution polymerizations and spin-coated on the glass slides to fabricate thin film with a thickness of similar to 1 mu m. It was found that the surface morphology of fluorinated thin films was strongly dependent on the crystallinity of polymers, In addition, the surface morphology was the most important factor to determine the optical transmittance of glass coated with the fluoropolymer thin film. As decreasing the crystallinity of the polymer by introducing HFP with a bulky CF3 moiety, the surface of thin film became flattened and the transmittance of visible light was increased by reducing scattering.

机译：偏二氟乙烯的均聚物及其包含六氟丙烯的共聚物（HFP）是通过自由基溶液聚合反应制备的，并旋涂在载玻片上以制造厚度约为1微米的薄膜。发现氟化薄膜的表面形态强烈依赖于聚合物的结晶度。另外，表面形态是确定涂覆有氟聚合物薄膜的玻璃的光学透射率的最重要因素。通过引入具有大体积CF 3部分的HFP而降低聚合物的结晶度时，薄膜的表面变得平坦，并且通过减少散射来增加可见光的透射率。

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《Journal of Applied Polymer Science》 |2009年第5期|共7页
作者
Lee SG; Lee JS; Ha JW; Park IJ; Lee SB; Lee JD;
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crystallinity; surface morphology; optical transmittance; poly(vinylidene fluoride-co-hexafluoropropylene);

机译：结晶度;表面形貌;透光率;聚偏二氟乙烯-共六氟丙烯;

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1. Effect of Crystallinity on Surface Morphology and Light Transmittance of Poly(vinylidene fluoride-co-hexafluoropropylene) Thin Film [J] . Lee SG, Lee JS, Ha JW, Journal of Applied Polymer Science . 2009,第5期

机译：结晶度对聚偏二氟乙烯-共-六氟丙烯薄膜的表面形貌和透光率的影响
2. The Crystalline Microstructure, Surface Morphology and Ferroelectric Properties of β-Phase in the Poly(Vinylidene Fluoride)/Carbon Nanotubes (PVDF/CNTs) Composite Thin Film Using the Electrospinning Approach [J] . Anh Do Phuong, Hoa Tran Thi Nhu, Van Thinh Nguyen, Materials Focus . 2018,第6期

机译：静电纺丝法在聚（偏二乙烯基）/碳纳米管（PVDF / CNT）复合薄膜中β相的结晶微观结构，表面形貌和铁电性能
3. Comparison of crystalline thin poly(vinylidene (70 percent)-trifluoroethylene (30 percent)) copolymer films with short chain poly(vinylidene fluoride) films [J] . J. Choi, E. Morikawa, S. Ducharme Materials Letters . 2005,第28期

机译：结晶性聚偏二氟乙烯（70％）-三氟乙烯（30％）薄膜与短链聚偏二氟乙烯薄膜的比较
4. Crystallinity Effect on Electric Energy Storage in Miscible Poly(vinylidene fluoride-co-hexafluoropropylene)/ Poly(methyl methacrylate) Blend Films [C] . Jung-Kai Tseng, Craig Lewis, Lei Zhu PMSE Symposia . 2011

机译：在混溶性聚（偏二氟乙烯 - 共六氟丙烯）/聚（甲基丙烯酸甲酯）共混薄膜中的电能储存结晶性效果
5. Morphological Effects on Spin-Dependent Electronic Processes in Poly[9,9-Dioctylfluorenyl-2,7-Diyl] Thin Film Organic Light Emitting Diodes. [D] . Miller, Richards G., III. 2017

机译：聚[9,9-二辛基芴基-2,7-二基]薄膜有机发光二极管中自旋相关电子过程的形态学影响。
6. Preparation and Characterization of Novel Polymer-Based Gel Electrolyte for Dye-Sensitized Solar Cells Based on poly(vinylidene fluoride-co-hexafluoropropylene) and poly(acrylonitrile-co-butadiene) or poly(dimethylsiloxane) bis(3-aminopropyl) Copolymers [O] . Krzysztof Artur Bogdanowicz, Dariusz Augustowski, Justyna Dziedzic, 2020

机译：基于聚偏二氟乙烯-共六氟丙烯和聚（丙烯腈-丁二烯）或聚（二甲基硅氧烷）双（3-氨基丙基）共聚物的染料敏化太阳能电池聚合物基凝胶电解质的制备和表征
7. Anisotropic Electric Conductivity and Light Transmittance of Polypyrrole/Poly(vinylidene fluoride) Composites Film by Polymerization in Craze. [O] . Akiyoshi Takeno, Masaya Yoshimura, Minoru Miwa, 2001

机译：通过聚合在潮萃取中通过聚合聚合的聚吡咯/聚（偏二氟乙烯）复合材料膜的各向异性电导率和透光率。
8. Effect of Ultraviolet Radiation on Transparent Polymer Films as Determined Using in Situ FTIR-RA Spectroscopy. Volume II. Photophysics of Poly(Vinylidene Fluoride) Films [R] . Webb, J. D. 1984

机译：用原位FTIR-Ra光谱法测定紫外辐射对透明聚合物薄膜的影响。第二卷。聚（偏氟乙烯）薄膜的光物理学

Effect of Crystallinity on Surface Morphology and Light Transmittance of Poly(vinylidene fluoride-co-hexafluoropropylene) Thin Film

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