Synthesis of an Oxetane-Functionalized Hemispiroorthocarbonate Used as a Low-Shrinkage Additive in the Cationic Ultraviolet Curing of Oxetane Monomers

M. Sangermano; S. Giannelli; R. Acosta Ortiz; M. L. Berlanga Duarte; A. K. Rueda Gonzalez; A. E. Garcia Valdez

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Synthesis of an Oxetane-Functionalized Hemispiroorthocarbonate Used as a Low-Shrinkage Additive in the Cationic Ultraviolet Curing of Oxetane Monomers

机译：氧杂环丁烷官能化的半螺原碳酸酯的合成，用作低氧添加剂的氧杂环丁烷单体的阳离子紫外固化

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The synthesis of an hemispiroorthocarbonate functionalized with an oxetane group is reported. The obtained monomer was used as a slow shrinkable additive in the cationic ultraviolet curing of a commercially available dioxetane resin. We evidenced polymer network flexibilization by increasing the oxetane-functionalized hemispiroorthocarbonate content in the photocurable formulation. It was demonstrated that spiroorthocarbonate acted as a shrinkage reduction additive and reached expansion on volume after polymerization in the presence of 50 wt % of the functionalized spiroorthocarbonate.

机译：据报道，用氧杂环丁烷基团官能化的半螺原碳酸酯的合成。所获得的单体用作市售二氧杂环丁烷树脂的阳离子紫外线固化中的缓慢收缩添加剂。我们通过增加光固化制剂中氧杂环丁烷官能化的半螺碳酸酯的含量证明了聚合物网络的柔韧性。已经证明，在50wt％的官能化原碳酸酯的存在下，螺原碳酸酯充当减缩添加剂并在聚合后达到体积膨胀。

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《Journal of Applied Polymer Science》 |2009年第3期|共8页
作者
M. Sangermano; S. Giannelli; R. Acosta Ortiz; M. L. Berlanga Duarte; A. K. Rueda Gonzalez; A. E. Garcia Valdez;
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正文语种 eng
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cationic polymerization; coatings; photopolymerization;

机译：阳离子聚合;涂料;光聚合;

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1. Synthesis of an Oxetane-Functionalized Hemispiroorthocarbonate Used as a Low-Shrinkage Additive in the Cationic Ultraviolet Curing of Oxetane Monomers [J] . M. Sangermano, S. Giannelli, R. Acosta Ortiz, Journal of Applied Polymer Science . 2009,第3期

机译：氧杂环丁烷官能化的半螺原碳酸酯的合成，用作低氧添加剂的氧杂环丁烷单体的阳离子紫外固化
2. Synthesis of Perfluorinated Oxetane and Surface Properties of Its Cationic UV Cured Coating as a Reactive Additive [J] . ZHAN Fu, ZHANG Yong, SHI Wen-fang 高等学校化学研究（英文版） . 2012,第003期

机译：全氟化氧杂环丁烷的合成及其阳离子型紫外固化涂料的表面性能
3. Ultraviolet-ultraviolet dual-cure process based on acrylate oxetane monomers [J] . El-Ghayoury A., Boukaftane C., De Ruiter B., Journal of Polymer Science, Part A. Polymer Chemistry . 2003,第4期

机译：基于丙烯酸氧杂环丁烷单体的紫外线-紫外线双固化工艺
4. Dual Cure Systems Based on Photo and Thermal Polymerization of Acrylate Oxetane Monomers [C] . M. Sangermano, M. Manea, R. Bongiovanni Annual Meeting Program of the FSCT . 2004

机译：基于丙烯酸乙烷单体的光和热聚合的双固化系统
5. Reactivity studies of oxirane and oxetane monomers in photoinitiated cationic polymerizations. [D] . Bulut, Umut. 2007

机译：环氧乙烷和氧杂环丁烷单体在光引发的阳离子聚合中的反应性研究。
6. Effect of Very High Charge Density and Monomer Constitution on the Synthesis and Properties of Cationic Polyelectrolytes [O] . Hamideh Ahmadloo, Ricardo Losada, Christine Wandrey 2016

机译：极高的电荷密度和单体组成对阳离子聚电解质的合成和性能的影响
7. The Copolymerization of the Vinyl Monomer with a Cyclic Compound. I. The Cationic Copolymerization of Some Vinyl Monomers with 3,3-Bis (chloromethyl) oxetane [O] . Shuzo Aoki, Yoshiyuki Harita, Takayuki Otsu, 1965

机译：乙烯基单体用环状化合物的共聚。 I.用3,3-双（氯甲基）氧乙烷的一些乙烯基单体的阳离子共聚
8. Synthesis of Carborane-Oxetane Monomers and Their Polymerization [R] . Manser, G. E. 1988

机译：碳硼烷 - 氧杂环丁烷单体的合成及其聚合

Synthesis of an Oxetane-Functionalized Hemispiroorthocarbonate Used as a Low-Shrinkage Additive in the Cationic Ultraviolet Curing of Oxetane Monomers

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