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Structure and Properties of Hemp Fabric Treated with Chitosan and Dyed with Mixed Epoxy-Modified Silicone Oil

机译:壳聚糖处理混合环氧改性硅油染麻织物的结构和性能

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To enhance the color yield and improve the soft handle, hemp fabrics were treated with chitosan of molecular weight 4200 and degree of deacetylation 0.90, and then dyed using Remazol Brillant Blue R with mixed epoxy-modified silicone oil in different volume ratios. The structural changes in hemp fibers were investigated by means of scanning electron microscope, FTIR, TG, DSC, and XRD. The properties of tensile, bending, dyeing, and color fastness for hemp fabric were also studied. The results showed that when compared with the untreated hemp fiber, the thermal performance of chitosan/silicone oil-modified hemp fiber changed and the percent residual weight increased in the range of temperature 25-550 degrees C. The crystal grain size decreased and the degree of crystallization increased. For chitosan/silicone oil-treated hemp fabric, the flexural stiffness and tensile properties degraded. The maximum color yield (K/S value) was obtained when the volume ratio of dyeing liquor to silicone oil was 2 : 1. The color fastnesses to rubbing and wet scrubbing were also improved.
机译:为了提高颜色产量并改善柔软手感,对麻织物进行了分子量为4200的脱乙酰壳多糖处理,脱乙酰度为0.90,然后使用Remazol Brillant Blue R和混合体积比的混合环氧改性硅油进行染色。通过扫描电子显微镜,FTIR,TG,DSC和XRD研究了大麻纤维的结构变化。还研究了大麻织物的拉伸,弯曲,染色和色牢度的特性。结果表明,与未处理的大麻纤维相比,壳聚糖/硅油改性的大麻纤维的热性能发生了变化,并且在温度25-550℃范围内残余重量百分数增加了。的结晶增加。对于壳聚糖/硅油处理的大麻织物,其弯曲刚度和拉伸性能下降。当染色液与硅油的体积比为2∶1时,获得最大的色产率(K / S值)。耐摩擦色牢度和湿法擦色牢度也得到改善。

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