New Copper Phthalocyanine Oligomers for High Dielectric Constant Polymer Films

Saha R; Mandal BK

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New Copper Phthalocyanine Oligomers for High Dielectric Constant Polymer Films

机译：用于高介电常数聚合物薄膜的新型酞菁铜低聚物

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We report here the synthesis of two new oligomeric copper phthalocyanine (CuPc) derivatives by esterification of the corresponding carboxylic acids with tri(ethylene glycol) monomethyl ether. The solubility of these derivatives in N,N'-dimethylformamide (DMF) enabled us to perform dielectric studies with poly(vinylidene fluoride-trifluoroethylene) P(VDF-TrFE), acting as the host polymer matrix. The highest room temperature dielectric constant achieved is 94 at 100 Hz, compared with 12 for the base polymer host matrix. Thermogravimetric analyzes of the polymer films showed that they are thermostable at 100 degrees C for a long period of time. Scanning electron microscopy (SEM) images of the films have also been analyzed.

机译：我们在这里报告了通过将相应的羧酸与三（乙二醇）单甲醚酯化而合成的两种新的低聚酞菁铜（CuPc）衍生物。这些衍生物在N，N'-二甲基甲酰胺（DMF）中的溶解度使我们能够使用聚（偏二氟乙烯-三氟乙烯）P（VDF-TrFE）作为主体聚合物基质进行介电研究。在100 Hz时达到的最高室温介电常数为94，而基础聚合物主体基质的室温介电常数为12。聚合物膜的热重分析表明，它们在100摄氏度的温度下可长期稳定。还分析了膜的扫描电子显微镜（SEM）图像。

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《Journal of Applied Polymer Science》 |2010年第1期|共7页
作者
Saha R; Mandal BK;
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正文语种 eng
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composites; dielectric properties; host-guest systems;

机译：复合材料;介电性能;主客体系统;

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1. New Copper Phthalocyanine Oligomers for High Dielectric Constant Polymer Films [J] . Saha R, Mandal BK Journal of Applied Polymer Science . 2010,第1期

机译：用于高介电常数聚合物薄膜的新型酞菁铜低聚物
2. Reply to the "Comment on "Synthesis and properties of a high dielectric constant copolymer of a copper phthalocyanine oligomer grafted to amino-capped polyimide"' by G. Mezei, Journal of Materials Chemistry C, 2019, 7, DOI: 10.1039/C8TC04076A [J] . Chen Linlin, Ding Yichun, Hou Haoqing Journal of Materials Chemistry, C. materials for optical and electronic devices . 2019,第16期

机译：回复“评论”的铜酞菁低聚物的高介电常数共聚物的合成和性质，覆盖氨基封端的聚酰亚胺，Mezei，Methinal Chemisty C，2019,7，Doi：10.1039 / C8TC04076A
3. Comment on "Synthesis and properties of high dielectric constant copolymer of a copper phthalocyanine oligomer grafted to amino-capped polyimide" by L. Chen, Y. Ding, T. Yang, C. Wan and H. Hou, J. Mater. Chem. C, 2017, 5, 8371 [J] . Mezei Gellert Journal of Materials Chemistry, C. materials for optical and electronic devices . 2019,第16期

机译：评注L. Chen，Y. Ding，T. Yang，C.Wan，J. Mater。化学。 C，2017,5,8371
4. Femtosecond measurement of the third order nonlinear optical coefficients of CuPc (copper phthalocyanine), CoPc (cobalt phthalocyanine) and ZnPc (zinc phthalocyanine) thin films using Z-scan measurement method [C] . Shin, M.J., Wu, . 1999

机译：飞秒测量ZP扫描法测量CuPc（铜酞菁），CoPc（钴酞菁）和ZnPc（锌酞菁）薄膜的三阶非线性光学系数
5. Study of PECVD films containing flourine and carbon and diamond like carbon films for ultra low dielectric constant interlayer dielectric applications. [D] . Sundaram, Nandini Ganapathy. 2016

机译：用于超低介电常数层间电介质应用的含氟和碳的PECVD膜和类金刚石碳膜的研究。
6. Giant Dielectric Constant of Copper Nanowires/AmorphousSiO2 Composite Thin Films for Supercapacitor Application [O] . Anupam Maity, Subha Samanta, Shubham Roy, 2020

机译：铜纳米线/非晶态的巨介电常数用于超级电容器的SiO2复合薄膜
7. Fabrication of selectively functionalized-graphene reinforced copper phthalocyanine nanocomposites with low dielectric loss and high dielectric constant [O] . Zicheng Wang, Renbo Wei, Xiaobo Liu 2017

机译：具有低介电损耗和高介电常数的选择性官能化 - 石墨烯增强铜酞菁纳米复合材料的制备
8. Preparation and Characterization of High Dielectric Constant Polymer Films. [R] . J. Szabo N. Harrison 2002

机译：高介电常数聚合物薄膜的制备与表征。

New Copper Phthalocyanine Oligomers for High Dielectric Constant Polymer Films

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