首页> 外文期刊>Journal of Applied Polymer Science >Thermal decomposition of cellulose/synthetic polymer blends containing grafted products. V. cellulose/polystyrene blends
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Thermal decomposition of cellulose/synthetic polymer blends containing grafted products. V. cellulose/polystyrene blends

机译:含有接枝产物的纤维素/合成聚合物共混物的热分解。五,纤维素/聚苯乙烯共混物

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摘要

Homogeneous grafting of styrene onto cellulose was carried out in a dimethylacetamide/lithium chloride solvent system. The grafted products were added to cellulose/polystyrene (PS) blends as compatibilizers. The thermal decomposition behavior of the blends was investigated by thermogravimetry. The thermal stability of the blends decreased with an increase in grafted product content. The crystallinity of the blends decreased with grafted product content. The microphase-separated structures of the blends became finer with grafted product content. The glass transition temperatures for cellulose and PS in the blends were lowered with grafted product content. Differences in thermal decomposition behavior of the blends were correlated with compatibility. Thermogravimetry was effective for compatibility estimation in cellulose/PS blends containing grafted products.
机译:苯乙烯在纤维素上的均相接枝是在二甲基乙酰胺/氯化锂溶剂体系中进行的。将接枝产物作为增容剂添加到纤维素/聚苯乙烯(PS)混合物中。通过热重法研究了共混物的热分解行为。共混物的热稳定性随着接枝产物含量的增加而降低。共混物的结晶度随接枝产物含量的降低而降低。共混物的微相分离结构随着接枝产物的含量而变得更细。共混物中纤维素和PS的玻璃化转变温度随着接枝产物的含量而降低。共混物的热分解行为差异与相容性相关。热重分析法有效地评估了含有接枝产物的纤维素/ PS共混物的相容性。

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