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Thermal stability and crystalline of electrospun polyamide 6/organo-montmorillonite nanofibers

机译:电纺聚酰胺6 /有机蒙脱土纳米纤维的热稳定性和晶体

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摘要

This research is mainly to investigate the thermal and crystalline differences between polyamide 6/montmorillonite (PA6/MMT) and polyamide 6/organomontmorillonite (PA6/O-MMT) nanofibers, which were both prepared by electrospinning under the same process conditions. The structures of PA6/MMT and PA6/O-MMT nanofibers were observed by scanning electrical microscope. It was identified that the interval between O-MMT clays was increased in the PA6 matrix compared to that of MMT, which was detected by X-ray diffraction (XRD). The thermal properties of PA6 nanofibers contained O-MMT particles were more efficient than PA6/MMT nanofibers, that was verified using thermal gravimetric analysis. The crystalline properties of the electrospun nanofibers was investigated using differential scanning calorimeter and it was found that the degree of crystallinity in the PA6 nanofibers loaded with O-MMT was much higher than PA6/MMT and PA6 nanofibers.
机译:这项研究主要研究聚酰胺6 /蒙脱土(PA6 / MMT)和聚酰胺6 /有机蒙脱土(PA6 / O-MMT)纳米纤维之间的热和晶体差异,这两种纤维都是在相同的工艺条件下通过静电纺丝制备的。通过扫描电镜观察了PA6 / MMT和PA6 / O-MMT纳米纤维的结构。通过X射线衍射(XRD)检测发现,与MMT相比,PA6基体中O-MMT粘土之间的间隔增加了。包含O-MMT颗粒的PA6纳米纤维的热性能比PA6 / MMT纳米纤维的热性能更有效,这已通过热重分析得到了验证。使用差示扫描量热仪研究了电纺纳米纤维的结晶特性,发现负载有O-MMT的PA6纳米纤维的结晶度比PA6 / MMT和PA6纳米纤维高得多。

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