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Pongamia glabra seed oil based poly(urethane-fatty amide)

机译:Pongamia glabra种子油基聚氨基甲酸酯-脂肪酰胺

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摘要

Poly(urethane-fatty amide) (PUPGFA) was developed to use nonedible and nondrying Pongamia glabra seed oil. The resin was synthesized by the reaction of N,N-bis(2-hydroxyethyl) P. glabra fatty amide (HEPGFA) and tolylene-2,4- diisocyanate through a one-shot technique with a minimal amount (8-10%) of organic solvent. The structural elucidation of the resin was carried out by Fourier transform infrared (FTIR), ~1H-NMR, and ~(13)C-NMR spectroscopic techniques, whereas the curing mechanism was confirmed by FTIR spectroscopy and differential scanning calorimetry. The solubility of the resin was studied in different polar and nonpolar solvents. Thermal analysis was carried out by thermogravimetric analysis and differential thermal analysis techniques. Antibacterial studies of HEPGFA and PUPGFA were performed in the presence of Gram-negative Salmonella and Gram-positive Staphylococcus aureus bacteria by an agar diffusion method. Physicochemical, physicomechanical, and corrosion-resistance tests were performed by standard laboratory methods. PUPGFA had good physicomechanical properties, excellent chemical/corrosion resistance, and moderate antibacterial activities.
机译:聚(氨基甲酸酯脂肪酰胺)(PUPGFA)被开发为使用不可食用且不干燥的Pongamia glabra种子油。 N,N-双(2-羟乙基)P.glabra脂肪酰胺(HEPGFA)和甲苯-2,4-二异氰酸酯通过一次注射技术以最少的量(8-10%)反应合成树脂有机溶剂。通过傅里叶变换红外(FTIR),〜1H-NMR和〜(13)C-NMR光谱技术对树脂进行结构阐明,而固化机理则通过FTIR光谱和差示扫描量热法得以证实。研究了树脂在不同极性和非极性溶剂中的溶解度。通过热重分析和差热分析技术进行热分析。通过琼脂扩散法在革兰氏阴性沙门氏菌和革兰氏阳性金黄色葡萄球菌存在下进行HEPGFA和PUPGFA的抗菌研究。物理化学,物理机械和耐腐蚀测试是通过标准实验室方法进行的。 PUPGFA具有良好的物理机械性能,优异的耐化学/腐蚀性和适度的抗菌活性。

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