• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Polymer Science >Synthesis and photopolymerization of 2-(acryloyloxy)ethyl piperidine-1-carboxylate and 2-(acryloyloxy)ethyl morpholone-4-carboxylate
【24h】

Synthesis and photopolymerization of 2-(acryloyloxy)ethyl piperidine-1-carboxylate and 2-(acryloyloxy)ethyl morpholone-4-carboxylate

机译：2-（丙烯酰氧基）乙基哌啶-1-羧酸酯和2-（丙烯酰氧基）乙基吗啉酮-4-羧酸酯的合成和光聚合

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Two low-viscosity monomers, 2-(acryloyloxy)ethyl piperidine-1-carboxylate (AEPC II) and 2-(acryloyloxy)ethyl morpholone-4-carboxylate (AEMC), were synthesized with a non-isocyanate route. The photopolymerization kinetics was monitored by real-time infrared spectroscopy with a horizontal sample holder. The results indicated that AEPC II and AEMC had high ultraviolet curing rates and final double-bond conversions, which could reach 90 and 95%, respectively. The glass-transition temperatures of AEPC II/urethane acrylate resin (1/4 w/w), AEMC/urethane acrylate resin (1/4 w/w), and isobornyl acrylate/urethane acrylate resin (1/4 w/w) mixtures were 37.5, 45.6, and 57°C, respectively. The crosslink density of the AEMC/urethane acrylate resin (1/4 w/w) mixture was lower than that of the isobornyl acrylate/urethane acrylate resin (1/4 w/w) mixture.
机译：用非异氰酸酯途径合成了两种低粘度单体2-（丙烯酰氧基）乙基哌啶-1-甲酸酯（AEPC II）和2-（丙烯酰氧基）乙基吗啉酮-4-羧酸酯（AEMC）。用水平样品架通过实时红外光谱法监测光聚合动力学。结果表明，AEPC II和AEMC具有较高的紫外线固化速率和最终的双键转化率，分别可以达到90％和95％。 AEPC II /氨基甲酸酯丙烯酸酯树脂（1/4 w / w），AEMC /氨基甲酸酯丙烯酸酯树脂（1/4 w / w）和丙烯酸异冰片酯/氨基甲酸酯丙烯酸酯树脂（1/4 w / w）的玻璃化温度混合物分别为37.5、45.6和57℃。 AEMC /氨基甲酸酯丙烯酸酯树脂（1/4 w / w）混合物的交联密度低于丙烯酸异冰片酯/氨基甲酸酯丙烯酸酯树脂（1/4 w / w）混合物的交联密度。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号