首页> 外文期刊>Journal of Applied Polymer Science >Synthesis, characterization, and thermal analysis of two polymeric chromium ternary complexes with nitrilotriacetic acid and alanine or glycine
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Synthesis, characterization, and thermal analysis of two polymeric chromium ternary complexes with nitrilotriacetic acid and alanine or glycine

机译:两种含次氮基三乙酸和丙氨酸或甘氨酸的聚合铬三元配合物的合成,表征和热分析

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摘要

Two chromium ternary complexes with nitrilotriacetic acid as a primary ligand and alanine or glycine as secondary ligand were prepared in slightly acidic medium. The structure of these two complexes was characterized using elemental, thermal analysis, FTIR spectra, and the two complexes mass spectra. The spectroscopy data suggest that these two complexes were in polymeric form and have the monomeric unit H[Cr(HNTA)(Hala)(SO _4)] and H[Cr(HNTA)(Gly)(SO _4)] in which sulfate group act as a bidentate ligand linked between each monomeric unit for the same complex.
机译:在弱酸性介质中制备了以次氮基三乙酸为主要配体和丙氨酸或甘氨酸为次要配体的两种铬三元配合物。使用元素分析,热分析,FTIR光谱和两个配合物质谱对这两个配合物的结构进行了表征。光谱数据表明这两种络合物均为聚合物形式,并具有其中硫酸盐基团的单体单元H [Cr(HNTA)(Hala)(SO _4)]和H [Cr(HNTA)(Gly)(SO _4)]。充当连接同一复合物的每个单体单元之间的双齿配体。

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