Rapid monitoring of bisphenol - A diglycidyl ether formation through byproduct estimation: A study by Fourier transform infra-red spectroscopy

Sreenadhan J.; Guria C.

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Rapid monitoring of bisphenol - A diglycidyl ether formation through byproduct estimation: A study by Fourier transform infra-red spectroscopy

机译：通过副产物估算快速监测双酚-二缩水甘油醚的形成：傅里叶变换红外光谱法的研究

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For identification and quantification of desired and undesired products during epoxy resin formation, polymerization of bisphenol-A with the stoichiometric excess of epichlorohydrin is carried out using catalytic excess of alkali. The reaction is monitored using Fourier transform infra-red (FT-IR) spectroscopy technique. Major undesired products are unreacted monomers (bisphenol-A and epichlorohydrin) and byproducts (chlorine and α-glycol substituted diglycidal ether of bisphenol-A), whereas the desired product is only diglycidal ether of bisphenol-A. Molar concentrations of epichlorohydrin, bisphenol-A, diglycidal ether of bisphenol-A, chlorine substituted resin, and α-glycol substituted resin in the polymerization mixture are analyzed and quantified using FT-IR characteristic frequency bands at 925, 3448, 1344, 773, and 3641 cm~(-1), respectively. For optimal determination of process parameters on polymerization, effect of temperature and alkali loading on epoxy polymerization is carried to maximize the yield of diglycidal ether of bisphenol-A with simultaneous minimizing the byproducts formation.

机译：为了在环氧树脂形成过程中鉴定所需产物和不希望有的产物，使用催化过量的碱进行双酚-A与化学计量过量的表氯醇的聚合。使用傅立叶变换红外（FT-IR）光谱技术监控反应。主要不希望的产物是未反应的单体（双酚A和表氯醇）和副产物（双酚A的氯和α-乙二醇取代的二缩水甘油醚），而所需的产物仅仅是双酚A的二缩水甘油醚。使用FT-IR特征频带在925、3448、1344和773处分析和量化聚合混合物中表氯醇，双酚A，双酚A的二缩水甘油醚，氯取代的树脂和α-乙二醇取代的树脂的摩尔浓度和3641 cm〜（-1）。为了最佳地确定聚合过程中的工艺参数，温度和碱负荷对环氧聚合反应的影响可以最大化双酚A的二缩水甘油醚的收率，同时最大程度地减少副产物的生成。

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《Journal of Applied Polymer Science》 |2012年第5期|共12页
作者
Sreenadhan J.; Guria C.;
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正文语种 eng
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bisphenol-A diglycidyl ether; epoxy resin; FT-IR; polycondensation; reaction monitoring;

机译：双酚A二缩水甘油醚;环氧树脂;FT-IR;缩聚;反应监测;

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1. Rapid monitoring of bisphenol - A diglycidyl ether formation through byproduct estimation: A study by Fourier transform infra-red spectroscopy [J] . Sreenadhan J., Guria C. Journal of Applied Polymer Science . 2012,第5期

机译：通过副产物估算快速监测双酚-二缩水甘油醚的形成：傅里叶变换红外光谱法的研究
2. The Influence of Lixiviates on the Thermal Degradation of Diglycidyl Ether of Bisphenol A n=0/1,2-Diaminecyclohexane Studied by Dynamic Mechanical Analysis and Thermogravimetry-Fourier Transform Infrared Spectroscopy [J] . NUNEZ LISARDO, NUNEZ M.R., FRAGA F., Journal of Applied Polymer Science . 1999,第3期

机译：动态力学分析和热重-傅里叶变换红外光谱法研究利希维酮对双酚A n = 0 / 1,2-二胺环己烷二缩水甘油醚热降解的影响
3. Influence of lixiviates on the thermal degradation of diglycidyl ether of bisphenol A n = 0/1,2-diaminecyclohexane studied by dynamic mechanical analysis and thermogravimetry-Fourier transform infrared spectroscopy [J] . Nunez Lisardo, Fraga F., Taboada J., Journal of Applied Polymer Science . 1999,第3期

机译：动态力学分析和热重-傅里叶变换红外光谱法研究了利希韦酯对双酚A n = 0 / 1,2-二胺环己烷二缩水甘油醚热降解的影响
4. Study of the Cure of a Diglycidyl-ether of Bisphenol-a (DGEBA)/Triethylenetetramine (TETA) Epoxy System by Non-isothermal Differential Scanning Calorimetry (DSC) [C] . R. Losada, J. L. Mier, F. Barbadillo, International Materials Symposium . 2006

机译：非等温差分扫描量热法（DSC）对双酚-A（DGEBA）/三乙基丁二胺（TETA）环氧树脂体系的二炔酰醚的固化研究
5. A novel and rapid method to monitor the autoxidation of edible oils using Fourier transform infrared spectroscopy and disposable infrared cards. [D] . Russin, Ted Anthony. 2003

机译：一种使用傅立叶变换红外光谱法和一次性红外卡监控食用油自氧化的新颖而快速的方法。
6. Stabilities of bisphenol A diglycidyl ether bisphenol F diglycidyl ether and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry [O] . Natalia Szczepańska, Paweł Kubica, Błażej Kudłak, -1

机译：液相色谱-串联质谱法分析双酚A二缩水甘油醚双酚F二缩水甘油醚及其衍生物在受控条件下的稳定性
7. >Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy. [O] . Eva Vázquez Barreiro, Julio Seijas, Aida Jover Ramos, 2015

机译：<强>双酚A二缩水甘油醚（徽章）与傅立叶变换红外光谱锌卟啉的交联反应的研究。

Rapid monitoring of bisphenol - A diglycidyl ether formation through byproduct estimation: A study by Fourier transform infra-red spectroscopy

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