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Effect of zinc phenylphosphonate on the crystallization behavior of poly(l -lactide)

机译:苯基膦酸锌对聚(1-丙交酯)结晶行为的影响

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The effect of zinc phenylphosphonate (PPZn) on the crystallization behavior of poly(l-lactide) (PLLA) was investigated using differential scanning calorimetry (DSC) and Polarized Optical Microscopy (POM) measurements. The non-isothermal cold crystallization results showed that the addition of PPZn obviously decreased the cold crystallization temperature of PLLA and increased the degree of crystallinity of PLLA. The isothermal crystallization kinetics results showed that the crystallization rate of PLLA with small amount of PPZn was much higher than that of neat PLLA, and the half-time (t1/2) of PLLA/PPZn sample is far less than that of neat PLLA. As an effective nucleating agent, PPZn particles had also some influence on nucleation mechanism and crystal growth of PLLA.
机译:使用差示扫描量热法(DSC)和偏振光学显微镜(POM)测量研究了苯基膦酸锌(PPZn)对聚(l-丙交酯)(PLLA)结晶行为的影响。非等温冷结晶结果表明,PPZn的加入明显降低了PLLA的冷结晶温度,提高了PLLA的结晶度。等温结晶动力学结果表明,少量PPZn的PLLA结晶速率比纯PLLA的结晶速率高得多,且PLLA / PPZn样品的半衰期(t1 / 2)远小于纯PLLA。作为一种有效的成核剂,PPZn颗粒对PLLA的成核机理和晶体生长也有一定影响。

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