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Facile fabrication of conductive ultrahigh molecular weight polyethylene fibers via mussel-inspired deposition

机译:通过贻贝启发沉积轻松制造导电超高分子量聚乙烯纤维

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摘要

The conductive ultrahigh molecular weight polyethylene fibers are fabricated by electroless silver plating. The extremely inert and smooth surfaces of fibers are first activated by dopamine self-polymerization. Then, metallic silver layers are deposited on the surface via electroless silver plating. The chemical composition, surface topography, and crystal structure of fibers are studied by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy, and X-ray diffraction (XRD), respectively. The XPS spectra certify the existence of polydopamine layer on surface. The XPS spectra and the XRD spectra prove that the silver particles deposited on the surface are pure in zero-value state and of high crystallinity. The resistance of the silver-coated fibers is 0.15 Ω/cm per bundle measured by two-point method. These conductive fibers with high conductivity are expected to use as the electrical wires.
机译:导电超高分子量聚乙烯纤维是通过化学镀银制成的。纤维极度惰性和光滑的表面首先通过多巴胺自聚合活化。然后,通过化学镀银将金属银层沉积在表面上。分别通过X射线光电子能谱(XPS),扫描电子显微镜和X射线衍射(XRD)研究了纤维的化学成分,表面形貌和晶体结构。 XPS光谱证明表面存在聚多巴胺层。 XPS光谱和XRD光谱证明,沉积在表面上的银颗粒为零值状态且纯度高。用两点法测得的每根束的涂银纤维的电阻为0.15Ω/ cm。这些具有高导电率的导电纤维有望用作电线。

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