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Preparation of hydrophilic polysulfone porous membrane by use of amphiphilic cellulose

机译:两亲性纤维素制备亲水性聚砜多孔膜

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摘要

A cellulose-based amphiphilic co-polymer with grafted myristyl groups was synthesized and used as an additive to modify polysulfone (PSf) membranes. Fourier transform infrared (FTIR) spectroscopy and Solid-state cross polarization magic angle spinning carbon-13 nuclear magnetic resonance (CP/MAS C-13 NMR) spectroscopy were used to characterize the structure of the synthesized amphiphilic cellulose. The good compatibility between amphiphilic co-polymer and PSf was confirmed by differential scanning calorimetry (DSC). Scanning electron microscopy (SEM) was conducted to inspect morphology of the membrane. Furthermore, Thermal performance was indicated by thermogravimetric analysis (TGA). Contact angle, flux and retention behavior were also measured in this work. The structural similarity enhanced compatibility among components by introducing flexible alkyl groups. According to the findings obtained from characterization, better compatibility of cellulose with PSf was achieved after amphiphilic treatment. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41664.
机译:合成了具有接枝肉豆蔻基的纤维素基两亲共聚物,并将其用作改性聚砜(PSf)膜的添加剂。利用傅立叶变换红外光谱(FTIR)和固态交叉极化魔角旋转碳13核磁共振(CP / MAS C-13 NMR)光谱表征了合成的两亲性纤维素的结构。通过差示扫描量热法(DSC)证实了两亲共聚物和PSf之间的良好相容性。进行扫描电子显微镜(SEM)以检查膜的形态。此外,热性能通过热重分析(TGA)表示。在这项工作中还测量了接触角,助焊剂和保留行为。通过引入柔性烷基,结构相似性增强了组分之间的相容性。根据表征获得的发现,两亲处理后,纤维素与PSf的相容性更好。 (c)2014 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,41664。

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