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The effect of an anhydride curing agent, an accelerant, and non-ionic surfactants on the electrical resistivity of graphene/epoxy composites

机译:酸酐固化剂,促进剂和非离子表面活性剂对石墨烯/环氧树脂复合材料电阻率的影响

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This study investigated different contents of an anhydride curing agent, an accelerant, and non-ionic surfactants on the electrical resistivity of cured graphene/epoxy composites. The anhydride curing agent was hexahydrophthalic anhydride (HHPA), the accelerant was 2-ethyl-4-methyl-1H-imidazole-1-propanenitrile (EMIP), and the non-ionic surfactants were Triton X surfactants with different numbers of polyethylene oxide (PEO) groups (m) that influence the electrical resistivity of cured graphene/epoxy composites. During the curing process, differential scanning calorimetry (DSC) was used to determine the effects of the extent of the crosslinking for different contents of the curing agent and how different enthalpy (H) on the electrical resistivity of the cured graphene/epoxy composites was then generated. The cured graphene/epoxy compositewhich consisted of a 1 : 0.85 weight ratio of epoxy resin and anhydride, a 0.5 wt % accelerant, and a 13 wt % graphene powderhad a low electrical resistivity of 11.68 cm and a thermal conductivity of 1.7 W/mK. In addition, the cured composites contained a 1.0 wt % polyethylene glycol p-isooctylphenyl ether (X-100) surfactant, which effectively decreased their electrical resistivity. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41975
机译:这项研究调查了不同含量的酸酐固化剂,促进剂和非离子表面活性剂对固化石墨烯/环氧树脂复合材料电阻率的影响。酸酐固化剂为六氢邻苯二甲酸酐(HHPA),促进剂为2-乙基-4-甲基-1H-咪唑-1-丙腈(EMIP),非离子表面活性剂为Triton X表面活性剂,具有不同数量的聚环氧乙烷( PEO)基团(m)影响固化的石墨烯/环氧树脂复合材料的电阻率。在固化过程中,使用差示扫描量热法(DSC)确定不同含量的固化剂的交联程度以及不同的焓(H)对固化的石墨烯/环氧树脂复合材料的电阻率的影响。产生。由重量比为1:0.85的环氧树脂和酸酐,0.5 wt%的促进剂和13 wt%的石墨烯粉末组成的固化石墨烯/环氧树脂复合物的电阻率低至11.68 cm,导热率 1.7 W / m K 。另外,固化的复合物包含1.0重量%的聚乙二醇对异辛基苯基醚(X-100)表面活性剂,其有效地降低了它们的电阻率。 (c)2015 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,41975

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