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The effect of wood-fiber type on the thermomechanical performance of a biodegradable polymer matrix

机译:木纤维类型对可生物降解聚合物基质热机械性能的影响

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The effect of type and content of wood fibers on the thermal, mechanical and rheological behavior of the commercial biodegradable polyester product, Ecovio (R) (BASF) is analytically studied. Ecovio (R) is basically a blend of poly(butylene adipate-terephthalate) copolyester (Ecoflex (R), BASF) and polylactide. Three different types of wood fibers, based either on raw cellulose (Arbocel) or selected conifers (Lignocel), with varying fiber size at various weight fractions were used for this purpose. The role of these fibers on the thermomechanical performance of Ecovio (R) was investigated in terms of several experimental techniques including scanning electron microscopy, differential scanning calorimetry, dynamic mechanical analysis, creep, tensile testing, and water uptake at room temperature. At the low wood fiber content (20 wt %), Lignocel composite's properties are predominant compared with the Arbocel composites. It has been found, that at this wood content, an efficient compatibility between matrix and fibers is achieved, leading to superior reinforcement. This trend is completely reversed at higher filler loading, probably due to the poor interfacial adhesion between the matrix and Lignocel occurring at 30 wt %. This behavior was supported by all the experimental methods employed. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42185.
机译:分析研究了木纤维的类型和含量对商业可生物降解聚酯产品Ecovio(BA)的热,机械和流变行为的影响。 Ecovio(R)基本上是聚(己二酸丁二酯-对苯二甲酸丁二醇酯)共聚酯(Ecoflex(BASF))和聚丙交酯的混合物。为此,使用了三种不同类型的木质纤维,基于原始纤维素(Arbocel)或选定的针叶树(Lignocel),它们在不同的重量分数下具有不同的纤维尺寸。通过几种实验技术,包括扫描电子显微镜,差示扫描量热法,动态力学分析,蠕变,拉伸试验和室温下的吸水率,研究了这些纤维对Ecovio(R)热机械性能的作用。在低木质纤维含量(20 wt%)下,与Arbocel复合材料相比,Lignocel复合材料的性能占主导地位。已经发现,在该木材含量下,实现了基体和纤维之间的有效相容性,从而导致了优异的增强。在较高的填充量下,这种趋势被完全逆转了,这可能是由于在30 wt%的基体和Lignocel之间存在不良的界面粘合。所有采用的实验方法均支持这种行为。 (c)2015 Wiley Periodicals,Inc. J. Appl。 Polym。科学2015,132,42185。

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