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Effect of dysprosium active ions on spectral properties of KGW single crystals

机译:active活性离子对KGW单晶光谱性质的影响

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摘要

Dysprosium (Dy) doped potassium gadolinium tungstate single crystals were grown by top seeded solution growth using K_2WO_4 as solvent. Two different concentrations of laser active ions were doped in the crystal. Crystals grown with lower growth rate using K_2WO_4 as solvent yielded better quality than that grown by K_2W_2O_7 as solvent. Growth conditions, like cooling rate and the rotation rate were optimized. Absorption studies confirm dominant absorption peaks in the visible as well as in near infrared regions. Photoluminescence reveals a strong yellow emission for the doped samples and the emission intensity of 3% Dy doped sample is 1.4 times higher than that of 1% Dy concentration in KGW. Raman spectra indicate the characteristic vibrational modes corresponding to the tungstate anion. The intensity of peaks in Raman spectra are increased with increase in concentration of Dy, in addition to a slight shift in Raman frequency.
机译:使用K_2WO_4作为溶剂通过顶部晶种溶液生长来生长掺(Dy)的钨酸钾potassium钨单晶。晶体中掺杂了两种不同浓度的激光活性离子。与使用K_2W_2O_7作为溶剂生长的晶体相比,使用K_2WO_4作为溶剂生长的晶体具有较低的生长速率。优化了生长条件,如冷却速度和旋转速度。吸收研究证实了可见光区域和近红外区域的主要吸收峰。光致发光显示掺杂样品的强黄色发射,并且3%Dy掺杂样品的发射强度是KGW中1%Dy浓度的1.4倍。拉曼光谱表明对应于钨酸根阴离子的特征振动模式。拉曼光谱中的峰强度随着Dy浓度的增加而增加,除了拉曼频率略有变化。

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