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Structure and photoluminescence properties of Ag-coated ZnO nano-needles

机译:涂银的ZnO纳米针的结构和光致发光性能

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摘要

A large number of zinc oxide (ZnO) nano-needles were synthesized by thermal oxidation of pure zinc. The surfaces of ZnO nano-needles were coated with a layer of Ag by pulse electro-deposition technique. The uncoated and coated ZnO nano-needles were characterized by using the X-ray diffraction and the scanning electron microscope (SEM). The results showed that the uncoated samples were close-packed hexagonal structure, which showed needle-like morphology. Their average diameter is about 40 nm, lengths up to 5 u,m. At the same time we observed that the prepared ZnO nano-needles have been coated with Ag successfully. The photoluminescence spectrums of ZnO nano-needles with Ag-coated and uncoated were analyzed, finding that the uncoated ZnO nano-needles have two fluorescence peaks at 388 nm and 470.8 nm, respectively, the relative intensity of 143.4 and 93.61; and the Ag-coated ZnO nano-needles showed a pair of strong peaks at 387.4 nm and 405.2 nm, the relative intensity of 1366 and 1305, respectively, indicating that the Ag-coated ZnO nano-needles can increase the absorption of UV light.
机译:通过纯锌的热氧化合成了大量的氧化锌(ZnO)纳米针。 ZnO纳米针的表面通过脉冲电沉积技术涂有一层Ag。通过使用X射线衍射和扫描电子显微镜(SEM)对未涂覆和涂覆的ZnO纳米针进行表征。结果表明,未涂覆的样品为密排六边形结构,呈针状形态。它们的平均直径约为40 nm,长度可达5 u,m。同时,我们观察到制备的ZnO纳米针已经成功被Ag包覆。对镀银和未镀银的ZnO纳米针的光致发光光谱进行分析,发现未镀锌的ZnO纳米针在388 nm和470.8 nm处有两个荧光峰,相对强度分别为143.4和93.61。包覆Ag的ZnO纳米针分别在387.4nm和405.2nm处有一对强峰,相对强度分别为1366和1305,表明包覆Ag的ZnO纳米针可以增加紫外光的吸收。

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