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Rapid solidification of silver-rich Ag-Cu-Zr alloys

机译:富银Ag-Cu-Zr合金的快速凝固

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摘要

In this work we explored the possibility of obtaining amorphous/crystalline composites in the Ag-rich side of the Ag-Cu-Zr ternary system exploiting the presence of a miscibility gap in the liquid. Four alloys with nominal composition (at.%) Ag_(75)Cu_(11)Zr_(14) (alloy A), Ag_(73)Cu_(17)Zr_(10) (alloy B), Ag_(47.5)Cu_(22.5)Zr_(30) (alloy C), Ag_(47.5)Cu_(30)Zr_(22.5) (alloy D) were investigated. The effect of the cooling rate and the composition on phase selection and microstructures was evaluated by comparing slowly cooled master ingots and rapidly quenched ribbons. Evidence of the liquid miscibility gap was observed only in alloys B and D, either in the master ingots and the ribbons. After rapid solidification, partial amorphisation was achieved for alloys C and D, where precipitates of the Ag-rich solid solution, showing various sizes, are dispersed in the amorphous matrix. A significant increase in hardness was achieved in the case of partially amorphous ribbons of alloys C and D (442 HV and 533 HV, respectively). Experimental results are discussed on the basis of the recently reassessed ternary Ag-Cu-Zr phase diagram.
机译:在这项工作中,我们探索了利用在液体中存在可混溶间隙的方法,在Ag-Cu-Zr三元系的富Ag侧获得非晶/晶体复合材料的可能性。四种标称成分(at。%)Ag_(75)Cu_(11)Zr_(14)(合金A),Ag_(73)Cu_(17)Zr_(10)(合金B),Ag_(47.5)Cu_(研究了22.5)Zr_(30)(合金C),Ag_(47.5)Cu_(30)Zr_(22.5)(合金D)。通过比较缓慢冷却的主锭和快速淬火的薄带,评估了冷却速率和组成对相选择和微结构的影响。仅在主锭和薄带中,仅在合金B和D中观察到液体混溶间隙的证据。快速凝固后,合金C和D实现了部分非晶化,富富银固溶体的沉淀物(显示各种尺寸)分散在无定形基体中。在合金C和D的部分非晶态薄带(分别为442 HV和533 HV)的情况下,硬度显着提高。根据最近重新评估的三元Ag-Cu-Zr相图讨论了实验结果。

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