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A new yellowish-green-emitting phosphor: Eu~(2+)-doped K_4CaSi_3O_9

机译:一种新的黄绿色发光荧光粉:Eu〜(2+)掺杂的K_4CaSi_3O_9

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摘要

Eu~(2+)-activated K_4CaSi_3O_9 phosphors were synthesized by conventional solid-state reaction. The phase formation was confirmed by X-ray powder diffraction measurements. The photoluminescence excitation and emission spectra were investigated. The phosphor presents bright yellowish-green-emitting luminescence under the excitation of UV and near UV light. The luminescence absolute quantum efficiencies of the phosphors with different Eu~(2+)-doping levels (1.0-5.0 mol%) were measured. The crystal structure and the site-occupancy of Eu~(2+) ions doped in K_4CaSi_3O_9 crystal lattice were discussed. Two different Eu~(2+) centers were assigned according to the crystal structure and the luminescence characteristics. The dependence of luminescence intensity on temperatures (25-150°C) was measured. The chromaticity coordinates and activation energy (ΔE) for thermal quenching were reported. The phosphor shows an excellent thermal stability on temperature quenching.
机译:通过常规固相反应合成了Eu〜(2+)活化的K_4CaSi_3O_9荧光粉。通过X射线粉末衍射测量证实了相形成。研究了光致发光的激发和发射光谱。磷光体在紫外光和近紫外光的激发下呈现出亮的黄绿色发光。测量了不同Eu〜(2+)掺杂水平(1.0〜5.0 mol%)的荧光粉的发光绝对量子效率。讨论了K_4CaSi_3O_9晶格中掺杂的Eu〜(2+)离子的晶体结构和位点占有率。根据晶体结构和发光特性分配了两个不同的Eu〜(2+)中心。测量了发光强度对温度(25-150℃)的依赖性。报道了用于热淬灭的色度坐标和活化能(ΔE)。磷光体在温度淬火时显示出极好的热稳定性。

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