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Investigation of photocatalytic activities over ZnO-TiO_2-reduced graphene oxide composites synthesized via microwave-assisted reaction

机译:微波辅助反应合成ZnO-TiO_2还原氧化石墨烯复合材料的光催化活性研究

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摘要

ZnO-TiO_2-reduced graphene oxide (RGO) composites were successfully synthesized by microwave-assisted reduction of graphite oxide in ZnO precursor solution with TiO_2 suspension using a microwave synthesis system. Their morphology, structure, and photocatalytic performance in the reduction of Cr(VI) were characterized by scanning electron microscopy, X-ray diffraction spectroscopy, and UV-vis absorption spectrophotometer. The results show that ZnO-TiO_2-RGO composites exhibit an enhanced photocatalytic performance in reduction of Cr(VI) with a maximum removal rate of 99.4% under UV light irradiation as compared with pure ZnO (58%) and ZnO-RGO (98%) composites due to the increased light absorption intensity and the reduction of electron-hole pair recombination in ZnO with the introduction of TiO_2.
机译:采用微波合成系统,以TiO_2为悬浮液,通过微波辅助还原ZnO前驱体溶液中的氧化石墨,成功合成了ZnO-TiO_2还原的氧化石墨烯(RGO)复合材料。通过扫描电子显微镜,X射线衍射光谱和紫外可见吸收分光光度计表征了它们的形态,结构和在还原Cr(VI)中的光催化性能。结果表明,与纯ZnO(58%)和ZnO-RGO(98%)相比,ZnO-TiO_2-RGO复合材料在紫外光照射下对Cr(VI)的还原具有增强的光催化性能,最大去除率为99.4%。 )是由于TiO_2的引入增加了ZnO中的光吸收强度并减少了电子-空穴对的重组。

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