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Atomic displacement and disorder in LiNbO3 single crystal caused by high-energy He-3 ion irradiation: an x-ray absorption spectroscopy study

机译:高能He-3离子辐照导致LiNbO3单晶的原子位移和无序:x射线吸收光谱研究

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摘要

Nb K-edge x-ray absorption fine structure spectra from a single lithium niobate (LN) crystal irradiated with high-energy He-3 ions of 41 MeV and from unexposed crystal as the reference material are compared. The differences in the x-ray absorption near edge structure (XANES) spectra are interpreted by simulating Nb K-edge XANES spectra with the FEFF8.2 code. It is found that displacements of Nb and Li atoms, as well as Li and O vacancies, are likely to cause structural disorder leading to change in the refractive index of LN and to diminished birefringence. This finding is in agreement with previous results obtained from SRIM-2003 simulations and transmission electron microscopy measurements.
机译:比较了用41 MeV的高能He-3离子辐照的单个铌酸锂(LN)晶体和未辐照的晶体作为参考材料的Nb K边缘x射线吸收精细结构光谱。通过使用FEFF8.2代码模拟Nb K边缘XANES光谱来解释X射线吸收近边缘结构(XANES)光谱中的差异。发现Nb和Li原子的位移以及Li和O的空位很可能引起结构混乱,从而导致LN的折射率发生变化并降低了双折射。这一发现与从SRIM-2003模拟和透射电子显微镜测量获得的先前结果一致。

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