PHOTOCHEMICAL REACTIONS OF TRANSITION METAL ORGANYL COMPLEXES WITH OLEFINS .11. PHOTOCHEMICALLY INDUCED C-C COUPLING OF TRICARBONYL-ETA(5)-2,4-DIMETHYL-2,4-PENTADIEN-1-YL-MANGANESE WITH 1-DIMETHYLAMINO-2-PROPYNE - SYNTHESIS OF A ETA(5)-7-DIMETHYLAMIN

Kreiter CG.; Frank W.; Reiss GJ.; Koch EC.

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PHOTOCHEMICAL REACTIONS OF TRANSITION METAL ORGANYL COMPLEXES WITH OLEFINS .11. PHOTOCHEMICALLY INDUCED C-C COUPLING OF TRICARBONYL-ETA(5)-2,4-DIMETHYL-2,4-PENTADIEN-1-YL-MANGANESE WITH 1-DIMETHYLAMINO-2-PROPYNE - SYNTHESIS OF A ETA(5)-7-DIMETHYLAMIN

机译：过渡金属有机化合物与烯烃的光化学反应.11。三苯甲酰基-ETA（5）-2,4-二甲基-2,4-戊二烯-1-基-锰与1-二甲基氨基-2-丙烯的光化学诱导C-C偶联-合成ETA（5）-7-二甲基丙氨酸

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UV irradiation of tricarbonyl-eta(5)-2,4-dimethyl-2,4-pentadien-1-yl-manganese (2) in THF at 208 K yields solvent-stabilized dicarbonyl-eta(5)-2,4-dimethyl-2,4-pentadien-1-yl-tetrahydrofurane-mangane se (3), which reacts in situ with two equivalents of 1-dimethylamino-2-propyne (4) to dicarbonyl-1-5-eta-2,4-dimethyl-(6-dimethylaminomethyl-N)-10-dimethylamino -deca-2,4,6,8-tetraen-1-yl-manganese (5). The crystal and molecular structure was determined by an X-ray diffraction analysis. Complex 5 crystallizes in the monoclinic space group P2(1)/c, a = 1109.9(2) pm, b = 836.0(2) pm, c = 2156.9(4) pm, beta = 93.23(3)degrees, V = 1.9982(7) nm(3), Z = 4. Complex 5 was also studied in solution by IR and NMR spectroscopy. A possible formation mechanism of 5 will be discussed. [References: 37]

机译：在208 K在THF中对三羰基-eta（5）-2,4-二甲基-2,4-戊二烯-1-基锰（2）进行UV辐射产生溶剂稳定的二羰基-eta（5）-2,4-二甲基-2,4-戊二烯-1-基-四氢呋喃-甘露聚糖本身（3），与两当量的1-二甲基氨基-2-丙炔（4）原位反应成二羰基-1-5-eta-2,4 -二甲基-（6-二甲基氨基甲基-N）-10-二甲基氨基-deca-2,4,6,8-四烯-1-基锰（5）。通过X射线衍射分析确定晶体和分子结构。配合物5在单斜空间群P2（1）/ c中结晶，a = 1109.9（2）pm，b = 836.0（2）pm，c = 2156.9（4）pm，beta = 93.23（3）度，V = 1.9982 （7）nm（3），Z =4。还通过IR和NMR光谱研究了溶液中的络合物5。将讨论可能的5的形成机理。 [参考：37]

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《Journal of Organometallic Chemistry》 |1995年第2期|共7页
作者
Kreiter CG.; Frank W.; Reiss GJ.; Koch EC.;
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Manganese; Pentadienyl; Photochemistry; Aminoalkyne; C-c-coupling; Organochromium pi-complexes; Ligand; Dienes; Phosphine; Chemistry;

机译：锰;戊二烯;光化学;氨基炔;C-c-偶联;有机铬pi络合物;配体;二烯;膦;化学;

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1. PHOTOCHEMICAL REACTIONS OF TRANSITION METAL ORGANYL COMPLEXES WITH OLEFINS .11. PHOTOCHEMICALLY INDUCED C-C COUPLING OF TRICARBONYL-ETA(5)-2,4-DIMETHYL-2,4-PENTADIEN-1-YL-MANGANESE WITH 1-DIMETHYLAMINO-2-PROPYNE - SYNTHESIS OF A ETA(5)-7-DIMETHYLAMIN [J] . Kreiter CG., Frank W., Reiss GJ., Journal of Organometallic Chemistry . 1995,第1a2期

机译：过渡金属有机化合物与烯烃的光化学反应.11。三苯甲酰基-ETA（5）-2,4-二甲基-2,4-戊二烯-1-基-锰与1-二甲基氨基-2-丙烯的光化学诱导C-C偶联-合成ETA（5）-7-二甲基丙氨酸
2. Photochemical reactions of transition metal organyl complexes with olefins XXII. Photoreactions of pentacarbonyl(#mu#-#eta#~(5:3)-4H-indenyl)-diiron(Fe-Fe) with alkynes—substituent controlled C-H transfer or C-C bond formation [J] . Cornelius G. Kreiter, Mike Packheiser, Walter Frank, Inorganica Chimica Acta . 1999,第1期

机译：过渡金属有机基配合物与烯烃XXII的光化学反应。五羰基（#mu＃-＃eta＃〜（5：3）-4H-茚基）-二铁（Fe-Fe）与炔烃的光反应-取代基控制的C-H转移或C-C键形成
3. Photochemical Reactions of Transition Metal Organyl Complexes with Olefins, 21 Photolysis of Tricarbonyl(#eta#~5-cyclohexadienyl)manganese in Tetrahydrofuran, Reactions with Cumulated Dienes [J] . Cornelius G. Kreiter, Norbert K. Wachter, Guido J. ReiB European journal of inorganic chemistry . 1999,第4期

机译：过渡金属有机基络合物与烯烃的光化学反应，三羰基（＃eta＃〜5-环己二烯基）锰在四氢呋喃中的光解，与累积的二烯的反应
4. Synthesis, Photophysical and Photochemical Properties of Arylborane Compounds and Their Metal Complexes [C] . Eri Sakuda 日本化学会春季年会講演予稿集 . 2018

机译：芳基硼烷化合物及其金属配合物的合成，光药和光化学性能
5. Organometallic Reaction Mechanisms: Olefin Polymerization Catalysis and Carbon-Hydrogen Bond Activation by Early Transition Metal Bisphenolate Complexes and Protonolysis of Bipyrimidine Platinum Methyl Complexes. [D] . Golisz, Suzanne R. 2010

机译：有机金属反应机理：早期过渡金属双酚盐配合物的烯烃聚合催化和碳氢键活化以及联嘧啶铂甲基配合物的质子分解。
6. A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis photochemical properties and influence of transition metal ions [O] . Falk Wehmeier, Jochen Mattay 2010

机译：全氟环戊烯基二芳基乙烯带有两个吡啶基部分–合成光化学性质和过渡金属离子的影响
7. Photochemical Reactions of Transition Metal Complexes Induced by Intramolecular Electron Transfer between Weakly Coupled Redox Centers [O] . Vogler Arnd 1988

机译：弱耦合氧化还原中心之间分子内电子转移引起的过渡金属配合物的光化学反应
8. Mechanisms of Photochemical Reactions of Transition Metal Complexes: Excited State Electron Transfer and Organometallic Photochemistry [R] . Wrighton, M. S. 1984

机译：过渡金属配合物光化学反应机理：激发态电子转移和有机金属光化学

PHOTOCHEMICAL REACTIONS OF TRANSITION METAL ORGANYL COMPLEXES WITH OLEFINS .11. PHOTOCHEMICALLY INDUCED C-C COUPLING OF TRICARBONYL-ETA(5)-2,4-DIMETHYL-2,4-PENTADIEN-1-YL-MANGANESE WITH 1-DIMETHYLAMINO-2-PROPYNE - SYNTHESIS OF A ETA(5)-7-DIMETHYLAMIN

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