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Evaluation of diagnostic ratios of phenanthrenes and chrysenes for the identification of severely weathered spilled oils from the simulation weathering and the Sinopec pipeline explosion at Huangdao, 2013

机译:评估纯植物和菊虱的诊断比例,以识别仿真风化的溢出油和黄岛,2013年黄岛的石化管道爆炸

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摘要

The composition and physical properties of spilled oil undergo great changes during a serious weathering process. This causes great difficulties for identifying the source of an oil spill. So stable and trustworthy diagnostic ratios (DRs) for the accurate identification of severely weathered spilled oils are very important. An explosion in the Sinopec pipeline happened on November 22, 2013 at Qingdao, China. Local beaches at Jiaozhou Bay were polluted by spilled oils. After the accident we collected original spilled oil samples from an area free from human interference near the oil leakage point. Synchronized with actual beach weathering, laboratory experiments were conducted to simulate oil weathering for 360 days by using the collected original spilled oil samples. Based on the t-test and the repeatability limit method, 46 diagnostic ratios (DRs) of phenanthrenes and chrysenes were screened. 18 DRs maintained remarkable stability during the simulated weathering experiments and field weathering process. These stable ratios can retain the characteristics of the oil source during weathering. They are very beneficial for improving the accuracy of identifying the source of severely weathered oil and can be used as an effective supplement to the existing index system for source identification.
机译:溢油的组成和物理性质在严重的耐候过程中经历了巨大变化。这导致识别漏油源的巨大困难。如此稳定,可靠的诊断比(DRS)用于准确识别严重风化的溢出的油非常重要。中国石化管道的爆炸发生在2013年11月22日在中国青岛。胶州湾的当地海滩被溢油污染。事故发生后,我们将原始溢出的油样从漏油点附近的人为干扰的区域。与实际海滩静音同步,通过使用收集的原始溢油样品进行实验室实验,以模拟160天的石油。基于T检验和可重复极限法,筛选了46个纯苯的诊断比(DRS)和Chrysenes。在模拟的风化实验和现场风化过程中,18次DRS保持显着稳定性。这些稳定的比率可以在风化期间保持油源的特性。它们非常有利于提高识别严重风化油来源的准确性,并且可以用作现有指标体系的有效补充以进行源识别。

著录项

  • 来源
    《RSC Advances》 |2018年第56期|共8页
  • 作者

    Han Bin; Zheng Li; Yu Shun;

  • 作者单位

    State Ocean Adm Inst Oceanog 1 Key Lab Marine Bioact Subst &

    Modern Analyt Techn Qingdao 266061 Peoples R China;

    State Ocean Adm Inst Oceanog 1 Key Lab Marine Bioact Subst &

    Modern Analyt Techn Qingdao 266061 Peoples R China;

    State Ocean Adm Inst Oceanog 1 Key Lab Marine Bioact Subst &

    Modern Analyt Techn Qingdao 266061 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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