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A facile route to magnetic mesoporous core-shell structured silicas containing covalently bound cyclodextrins for the removal of the antibiotic doxycycline from water

机译:含有共价结合的环糊精的磁性介孔核 - 壳结构二氧化硅的容纳途径,用于从水中除去抗生素的强霉素

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摘要

The excessive use of antibiotics has led to various environmental problems; the control and separation of these antibiotics are important in environmental science. Herein, a novel mesoporous nanocomposite, Fe3O4@SiO2@mSiO(2)-CD, has been synthesized for the removal of antibiotic compounds from aqueous media. The well-designed nanocomposite is composed of -cyclodextrin functionalized surfaces, ordered mesoporous silica shells with large radially oriented mesopores, and nonporous silica-coated magnetic cores (Fe3O4). The synergistic action of both the mesoporous structure and the accessible cavity of -cyclodextrin ensures the good adsorption of doxycycline. Furthermore, the Fe3O4@SiO2@mSiO(2)-CD nanocomposite can be collected, separated and easily recycled from aqueous solution using an external magnet.
机译:过量使用抗生素导致了各种环境问题; 这些抗生素的控制和分离在环境科学中很重要。 这里,已经合成了一种新型介孔纳米复合材料,Fe3O4 -SiO 2 @ MSIO(2)-CD,用于从水性介质中除去抗生素化合物。 精心设计的纳米复合材料由-cyclodextrin官能化表面组成,有序的介孔二氧化硅壳,具有大径向取向的偏孔,和无孔二氧化硅涂覆的磁芯(Fe3O4)。 介孔结构和-cyclodextrin的可偏心腔的协同作用确保了良好的催生素吸附。 此外,可以使用外部磁体收集,分离和容易从水溶液中收集,分离和容易地收集Fe3O4 @ SiO 2 @ MSIO(2)-Cd纳米复合材料。

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  • 来源
    《RSC Advances》 |2018年第55期|共10页
  • 作者单位

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

    Jilin Univ China Japan Union Hosp Changchun 130012 Jilin Peoples R China;

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

    Changchun Univ Technol Minist Educ Key Lab Adv Struct Mat Coll Mat Sci &

    Engn Changchun 130012 Jilin Peoples R China;

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  • 正文语种 eng
  • 中图分类 化学;
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