Copper-catalyzed one-pot domino reactions via C-H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal-organic framework catalysis

Ha V Dang; Hoang T B Le; Loan T B Tran; Hiep Q Ha; Ha V Le; Nam T S Phan

首页> 外文期刊>RSC Advances >Copper-catalyzed one-pot domino reactions via C-H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal-organic framework catalysis

【24h】

Copper-catalyzed one-pot domino reactions via C-H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal-organic framework catalysis

机译：通过C-H键活化的铜催化的单罐多米诺反应：在金属 - 有机骨架催化下，合成来自2-氨基苄基醇和偶联剂的3-苯甲酰喹啉

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A Cu-2(OBA)(2)(BPY) metal-organic framework was utilized as a productive heterogeneous catalyst for the synthesis of 3-aroylquinolines via one-pot domino reactions of 2-aminobenzylalcohols with propiophenones. This Cu-MOF was considerably more active towards the one-pot domino reaction than a series of transition metal salts, as well as nano oxide and MOF-based catalysts. The MOF-based catalyst was reusable without a significant decline in catalytic efficiency. To the best of our knowledge, the transformation of 2-aminobenzylalcohols to 3-aroylquinolines was not previously reported in the literature, and this protocol would be complementary to previous strategies for the synthesis of these valuable heterocycles.

机译：Cu-2（OBA）（2）（2）（2）（BPY）金属 - 有机骨架用作生产的非均相催化剂，用于合成3-植物喹啉，通过2-氨基苯醇的二氨基苯醇与偶体酮合成。该Cu-MOF比一系列过渡金属盐，以及纳米氧化物和基于MOF基催化剂相比，该Cu-MOF朝向单壶Domino反应更活跃。基于MOF基催化剂可重复使用，无需显着下降催化效率。据我们所知，先前在文献中报道了2-氨基苄基醇的转化，并未在文献中报告，本协议将与以前的合成这些有价值的杂环的策略互补。

著录项

来源
《RSC Advances》 |2018年第55期|共10页
作者
Ha V Dang; Hoang T B Le; Loan T B Tran; Hiep Q Ha; Ha V Le; Nam T S Phan;
展开▼
作者单位

HCMC Univ Technol Fac Chem Engn VNU HCM 268 Ly Thuong Kiet Dist 10 Ho Chi Minh City Vietnam;

HCMC Univ Technol Fac Chem Engn VNU HCM 268 Ly Thuong Kiet Dist 10 Ho Chi Minh City Vietnam;

HCMC Univ Technol Fac Chem Engn VNU HCM 268 Ly Thuong Kiet Dist 10 Ho Chi Minh City Vietnam;

HCMC Univ Technol Fac Chem Engn VNU HCM 268 Ly Thuong Kiet Dist 10 Ho Chi Minh City Vietnam;

HCMC Univ Technol Fac Chem Engn VNU HCM 268 Ly Thuong Kiet Dist 10 Ho Chi Minh City Vietnam;

HCMC Univ Technol Fac Chem Engn VNU HCM 268 Ly Thuong Kiet Dist 10 Ho Chi Minh City Vietnam;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Copper-catalyzed one-pot domino reactions via C-H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal-organic framework catalysis [J] . Ha V Dang, Hoang T B Le, Loan T B Tran, RSC Advances . 2018,第55期

机译：通过C-H键活化的铜催化的单罐多米诺反应：在金属 - 有机骨架催化下，合成来自2-氨基苄基醇和偶联剂的3-苯甲酰喹啉
2. Direct Synthesis of 4-Organylselanylpyrazoles by Copper-Catalyzed One-Pot Cyclocondensation and C-H Bond Selenylation Reactions [J] . Oliveira Daniela H., Aquino Thalita B., Nascimento Jose Edmilson R., Advanced synthesis & catalysis . 2015,第18期

机译：铜催化一锅环缩合反应和C-H键硒化反应直接合成4-有机基硒基吡唑
3. Domino N-H/C-H bond activation: Copper-catalyzed synthesis of nitrogen-bridgehead heterocycles using azoles and 1,4-dihalo-1,3-dienes [J] . Liao Q., Zhang L., Li S., Organic letters . 2011,第2期

机译：Domino N-H / C-H键活化：使用唑类和1,4-二卤代-1,3-二烯的铜催化合成氮桥头杂环
4. Ru/CeO2-Catalyzed C-C Bond Forming Reactions via Aromatic C-H Bond Activation [C] . Kenji Wada, Hiroki Miura, Saburo Hosokawa Symposium on Organometallic Chemistry . 2008

机译：Ru / CeO2催化的C-C键通过芳族C-H键活化形成反应
5. I. Catalysis of Intra- and Intermolecular Schmidt Reactions. II. Copper-Catalyzed Oxaziridine-Mediated C-H Bond Oxidation. III. Synthesis and Cytotoxic Evaluation of Withalongolide A Analogues. [D] . Motiwala, Hashim F. 2014

机译：I.分子内和分子间施密特反应的催化。二。铜催化的恶唑烷介导的C-H键氧化。三， Withalongolide A类似物的合成和细胞毒性评估。
6. Synthesis of Selenium-Quinone Hybrid Compounds with Potential Antitumor Activity via Rh-Catalyzed C-H Bond Activation and Click Reactions [O] . Guilherme A. M. Jardim, Eduardo H. G. da Cruz, Wagner O. Valença, 2018

机译：通过Rh催化的C-H键活化和Click反应合成具有潜在抗肿瘤活性的硒-醌杂化化合物
7. Highly Efficient Copper-Catalyzed Nitro-Mannich Type Reaction: Cross-Dehydrogenative-Coupling between sp3 C-H Bond and sp3 C-H Bond [O] . -1

机译：高效铜催化的硝基 - 曼尼奇型反应：SP3 C-H键和SP3 C-H键之间的交叉脱氢偶联

Copper-catalyzed one-pot domino reactions via C-H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal-organic framework catalysis

摘要

著录项

相似文献

相关主题

期刊订阅