首页> 外文期刊>RSC Advances >Bioinspired temporal supramolecular polymerization
【24h】

Bioinspired temporal supramolecular polymerization

机译:Bioinspired颞末分子聚合

获取原文
获取原文并翻译 | 示例
           

摘要

Thriving natural systems precisely regulate their complex chemical organizations in space and time by recruitment of a complex network of fuel-driven, kinetically controlled, out-of-equilibrium transformations. Indeed this provides an active, adaptive and autonomous smart actions & functions. In contrast, synthetic systems exhibit simpler behavior owing to thermodynamically driven supramolecular polymerization with no temporal modulation of spatial organization. Stimulated by an outstanding control that nature demonstrates, a drive towards artificial out-of-equilibrium systems with the ambition to program activation and duration of structural transformations has emerged. To realize this vision, overwhelming efforts across the globe have been initiated to design temporally programmed synthetic supramolecular polymers. In an attempt to contribute to this trending field, our supramolecular chemistry group has thoroughly investigated a structure-property relationship that determines the mechanism of supramolecular polymerization. Exploiting these mechanistic insights, along with a bio-inspired fuel-driven enzyme mediated approach, we further attempted to program supramolecular polymers in both structural and temporal regimes. We believe, nature is the inspiration to the current era challenges and it also provides with the solution, a fuel-driven approach to address these. In this account, we shall discuss the efforts made by our group to build generic concept to create temporally programmable supramolecular polymers.
机译:蓬勃发展的自然系统通过招聘复杂的燃料驱动,动力学控制,均衡转换,精确调节其复杂化学组织的空间和时间。事实上,这提供了一个活跃,自适应和自主的智能动作和功能。相比之下,由于没有空间组织的时间调制,合成系统由于热力学驱动的超分子聚合而表现出更简单的行为。通过突出的控制来刺激性质表明,朝着人为均衡系统的驱动,以便对节目激活和结构变换的持续时间进行了雄心壮志。为了实现这一愿景,已经开始在全球各地的压倒性地设计,以设计暂时编程的合成超分子聚合物。试图促进这种趋势领域,我们的超分子化学组彻底研究了确定超分子聚合机理的结构性质关系。利用这些机械洞察力,以及生物启发的燃料驱动酶介导的方法,我们进一步试图在结构和时间制度中编程超分子聚合物。我们相信,自然是目前时代挑战的灵感,它还提供了解决方案,一种解决这些问题的燃料驱动方法。在本账户中,我们将讨论我们小组制定的努力,建立通用概念,以创建时间上可编程的超分子聚合物。

著录项

  • 来源
    《RSC Advances》 |2018年第34期|共13页
  • 作者单位

    Jawaharlal Nehru Ctr Adv Sci Res Sch Adv Mat SAMat New Chem Unit Supramol Chem Lab Bangalore 560064 Karnataka India;

    Jawaharlal Nehru Ctr Adv Sci Res Sch Adv Mat SAMat New Chem Unit Supramol Chem Lab Bangalore 560064 Karnataka India;

    Jawaharlal Nehru Ctr Adv Sci Res Sch Adv Mat SAMat New Chem Unit Supramol Chem Lab Bangalore 560064 Karnataka India;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号