Synthesis of thermoresponsive oligo(ethylene glycol) polymers through radical ring-opening polymerization of vinylcyclopropane monomers

Stanojkovic Jovana; Oh Junki; Khan Anzar; Stuparu Mihaiela C.

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Synthesis of thermoresponsive oligo(ethylene glycol) polymers through radical ring-opening polymerization of vinylcyclopropane monomers

机译：通过乙烯基环丙烷单体的自由基开环聚合来合成热响应寡核苷酸（乙二醇）聚合物

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Polyvinylcyclopropanes are an old class of polymers typically known for their low polymerization-induced shrinkage properties. In this work, we show that they are capable of exhibiting a thermally triggered aggregation process in aqueous solutions. The phase transition is sharp, tunable within the temperature range of 25-46 degrees C, and relatively insensitive to environmental conditions. It is anticipated that this preliminary study will shine new light on polyvinylcyclopropanes and lead to new avenues in their studies and future application.

机译：聚乙烯基环丙烷是通常已知其低聚合诱导的收缩性能的旧聚合物。在这项工作中，我们表明它们能够在水溶液中表现出热触发的聚集过程。相转变在25-46摄氏度的温度范围内进行尖锐，可调谐，并且对环境条件相对不敏感。预计这项初步研究将在聚乙烯氨苄西丙烷上发出新的光线，并导致他们的研究中的新途径和未来的应用。

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《RSC Advances》 |2020年第4期|共5页
作者
Stanojkovic Jovana; Oh Junki; Khan Anzar; Stuparu Mihaiela C.;
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作者单位

Nanyang Technol Univ Sch Phys &

Math Sci Div Chem &

Biol Chem 21 Nanyang Link Singapore 637371 Singapore;

Korea Univ Dept Chem &

Biol Engn Seoul 02841 South Korea;

Korea Univ Dept Chem &

Biol Engn Seoul 02841 South Korea;

Nanyang Technol Univ Sch Phys &

Math Sci Div Chem &

Biol Chem 21 Nanyang Link Singapore 637371 Singapore;

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正文语种 eng
中图分类化学;
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1. Synthesis of thermoresponsive oligo(ethylene glycol) polymers through radical ring-opening polymerization of vinylcyclopropane monomers [J] . Stanojkovic Jovana, Oh Junki, Khan Anzar, RSC Advances . 2020,第4期

机译：通过乙烯基环丙烷单体的自由基开环聚合来合成热响应寡核苷酸（乙二醇）聚合物
2. RADICAL RING-OPENING POLYMERIZATION OF NOVEL VINYLCYCLOPROPANES DESIGNED AS LOW SHRINKAGE MONOMERS - STRUCTURE OF THE POLYMER, MECHANISM OF THE POLYMERIZATION, AND VOLUME CHANGE ON THE POLYMERIZATION [J] . Sanda F., Endo T., Takata T. Macromolecules . 1995,第5期

机译：设计为低收缩单体的新型乙烯基环丙烷的自由基开环聚合-聚合物的结构，聚合机理以及聚合反应的体积变化
3. Fluorescent, thermoresponsive oligo(ethylene glycol) methacrylate/9-(4- Vinylbenzyl)-9H-carbazole copolymers designed with multiple lcsts via nitroxide mediated controlled radical polymerization [J] . Lessard B.H., Ling E.J.Y., Mari? M. Macromolecules . 2012,第4期

机译：荧光性，热响应性的低聚（乙二醇）甲基丙烯酸甲酯/ 9-（4-乙烯基苄基）-9H-咔唑共聚物，通过氮氧化物介导的受控自由基聚合与多个lcst设计
4. Novel Monomer Synthesis of Trimethylene Carbonate Derivative Directly Connected with Oligo(ethylene glycol) and Its Polymer Characterization [C] . Hiroharu Ajiro, Yoshikazu Takahashi, Tomoko Fujiwara PMSE Symposia . 2012

机译：二甲基碳酸酯衍生物与寡核苷酸（乙二醇）直接连接的新型单体合成及其聚合物表征
5. Oligo(ethylene glycol) Grafted Polyester Polymer Brushes as Dynamic Surfaces [D] . Stevens, Cameron Lee. 2018

机译：寡核苷酸（乙二醇）接枝聚酯聚合物刷作为动态表面
6. Preparation of Thermoresponsive Polymer Nanogels of Oligo(Ethylene Glycol) Diacrylate-Methacrylic Acid and Their Property Characterization [O] . Hongyan Cao, Fenghao Guo, Zhiyong Chen, 2018

机译：丙烯酸二乙二醇酯-甲基丙烯酸热敏聚合物纳米凝胶的制备及性能表征
7. Poly(oligo(ethylene glycol) vinyl acetate)s : a versatile class of thermoresponsive and biocompatible polymers [O] . Hedir, Guillaume, Arno, Maria Chiara, Langlais, Marvin, 2017

机译：聚（低聚（乙二醇）乙酸乙烯酯）：一类通用的热响应性和生物相容性聚合物

Synthesis of thermoresponsive oligo(ethylene glycol) polymers through radical ring-opening polymerization of vinylcyclopropane monomers

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