Nanohybrids of reduced graphene oxide and cobalt hydroxide (Co(OH)(2)|rGO) for the thermal decomposition of ammonium perchlorate

Abarca Gabriel; Rios Paulina L.; Povea Paula; Cerda-Cavieres Christopher; Morales-Verdejo Cesar; Arroyo Juan L.; Camarada Maria B.

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Nanohybrids of reduced graphene oxide and cobalt hydroxide (Co(OH)(2)|rGO) for the thermal decomposition of ammonium perchlorate

机译：氧化石墨烯和氢氧化钴（Co（OH）（2）| RGO）的纳米组织用于高氯酸铵的热分解

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The catalytic activity of nanoparticles of cobalt hydroxide supported on reduced graphene oxide, Co(OH)(2)|rGO, was studied for the decomposition of ammonium perchlorate (AP), the principal ingredient of composite solid propellants. Co(OH)(2)|rGO was synthesized by anin situreduction method, which avoided the application of extremely high temperatures and harsh processes. rGO stabilized the nanoparticles effectively and prevented their agglomeration. The performance of Co(OH)(2)|rGO as a catalyst was measured by differential scanning calorimetry. Co(OH)(2)|rGO affected the high-temperature decomposition (HTD) of AP positively, decreasing the decomposition temperature of AP to 292 degrees C, and increasing the energy release to 290 J g(-1). The diminution of the HTD of AP by Co(OH)(2)|rGO is in between the best values reported to date, suggesting its potential application as a catalyst for AP decomposition.

机译：研究了氢氧化物钴纳米甲基氧化钴，CO（OH）（2）| RGO的催化活性，用于分解高氯酸铵（AP），复合固体推进剂的主要成分。 CO（OH）（2）| RGO由Anin Bisueuction方法合成，避免了极高的温度和恶劣工艺的应用。 Rgo有效地稳定纳米颗粒并防止它们的聚集。通过差示扫描量热法测量作为催化剂的CO（OH）（2）（2）（2）（2）的性能。 CO（OH）（2）| RGO对AP的高温分解（HTD）正积极，将AP的分解温度降低至292℃，并将能量释放增加到290Jg（-1）。通过CO（OH）（2）| RGO的HTD的降低在迄今为止报告的最佳值之间，建议其作为AP分解的催化剂的潜在应用。

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《RSC Advances》 |2020年第39期|共8页
作者
Abarca Gabriel; Rios Paulina L.; Povea Paula; Cerda-Cavieres Christopher; Morales-Verdejo Cesar; Arroyo Juan L.; Camarada Maria B.;
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作者单位

Univ Bernardo OHiggins Escuela Obstet &

Puericultura Ctr Integrat Biol &

Quim Aplicada CIBQA Santiago 8370993 Chile;

Univ Mayor Ctr Nanotecnol Aplicada Fac Ciencias Santiago 8580745 Chile;

Inst Invest &

Control Ejercito Chile IDIC Lab Mat Energet Av Pedro Montt 2136 Santiago 8370899 Chile;

Univ Mayor Ctr Nanotecnol Aplicada Fac Ciencias Santiago 8580745 Chile;

Univ Bernardo OHiggins Escuela Obstet &

Puericultura Ctr Integrat Biol &

Quim Aplicada CIBQA Santiago 8370993 Chile;

Inst Invest &

Control Ejercito Chile IDIC Lab Mat Energet Av Pedro Montt 2136 Santiago 8370899 Chile;

Univ Mayor Ctr Nanotecnol Aplicada Fac Ciencias Santiago 8580745 Chile;

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正文语种 eng
中图分类化学;
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1. 还原氧化石墨烯负载氧化钴杂化纳米催化剂的合成及其对一氧化碳氧化的催化性能 [J] . 王燕, 陈泽华, 黄静, 中国有色金属学报：英文版 . 2018,第011期
2. Nanohybrids of reduced graphene oxide and cobalt hydroxide (Co(OH)(2)|rGO) for the thermal decomposition of ammonium perchlorate [J] . Abarca Gabriel, Rios Paulina L., Povea Paula, RSC Advances . 2020,第39期

机译：氧化石墨烯和氢氧化钴（Co（OH）（2）| RGO）的纳米组织用于高氯酸铵的热分解
3. Facile preparation of rGO/MFe2O4 (M = Cu, Co, Ni) nanohybrids and its catalytic performance during the thermal decomposition of ammonium perchlorate [J] . Wang Weiran, Zhang Dongxiang RSC Advances . 2018,第56期

机译：瓦尔夫/ MFE2O4（M = Cu，Co，Ni）纳米组织的含量制备及其在高氯酸铵热分解过程中的催化性能
4. Facile preparation of rGO/MFe2O4 (M = Cu, Co, Ni) nanohybrids and its catalytic performance during the thermal decomposition of ammonium perchlorate [J] . Weiran Wang, Dongxiang Zhang RSC Advances . 2018,第56期

机译：rGO / MFe2O4（M = Cu，Co，Ni）纳米杂合物的简便制备及其在高氯酸铵热分解过程中的催化性能
5. Hydrothermally Synthesized Reduced Graphene Oxide/ Nickel Hydroxide (rGO/Ni(OH)_2) Nanocomposite: A Promising Material in Dye Removal [C] . Suryakanti Debata, Trupti R. Das, Rashmi Madhuri, DAE Solid State Physics Symposium . 2017

机译：水热合成的石墨烯氧化物/氢氧化镍（RGO / Ni（OH）_2）纳米复合材料：去除染料中有希望的材料
6. KINETICS OF THE THERMAL DECOMPOSITION OF AMMONIUM PERCHLORATE. [D] . SIEGMUND, ROBERT FRED. 1970

机译：高氯酸铵热分解的动力学。
7. Constructing Sheet-On-Sheet Structured Graphitic Carbon Nitride/Reduced Graphene Oxide/Layered MnO2 Ternary Nanocomposite with Outstanding Catalytic Properties on Thermal Decomposition of Ammonium Perchlorate [O] . Jianhua Xu, Dongnan Li, Yu Chen, 2017

机译：构建具有高催化热分解高氯酸铵性能的片状片状结构氮化碳/还原石墨烯/层状MnO2三元纳米复合材料
8. Nanohybrids of reduced graphene oxide and cobalt hydroxide (Co(OH)2rGO) for the thermal decomposition of ammonium perchlorate [O] . Gabriel Abarca, Paulina L. Ríos, Paula Povea, 2020

机译：氧化石墨烯和氢氧化钴（CO（OH）2 RGO）的纳米组织用于高氯酸铵的热分解

Nanohybrids of reduced graphene oxide and cobalt hydroxide (Co(OH)(2)|rGO) for the thermal decomposition of ammonium perchlorate

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