Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC-Au(i) complex

Zhan Licheng; Zhang Gengtao; Wang Jiwei; Zhang Jun

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Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC-Au(i) complex

机译：基于四碳喹啉的手性卡贝蛋白前体和相关手性NHC-Au（i）复合物合成

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Four tetrahydroquinoline-based chiral carbene precursors were synthesized using unsymmetricalN,N '-diarylformamidines and chiral 2-allyloxiranes as starting materials. A representative NHC-gold complex has been prepared and fully characterized, the crystal structure of which reveals an intramolecular AuMIDLINE HORIZONTAL ELLIPSISH-C(sp(3)) interaction between Au(i) and the hydrogen atom of the isopropyl moiety in theN-aryl group.

机译：基于四种四碳喹啉的手性卡贝尔前体，使用非对称N，N'-二芳基甲络脒和手性2-烯丙烷烃作为原料合成。已经制备和完全表征了代表性的NHC-金络合物，其晶体结构揭示了分子内Aumidline水平椭圆形式-C（SP（3））与然后芳基的异丙基部分的氢原子之间的相互作用团体。

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来源
《RSC Advances》 |2020年第58期|共4页
作者
Zhan Licheng; Zhang Gengtao; Wang Jiwei; Zhang Jun;
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作者单位

East China Univ Sci &

Technol Joint Int Res Lab Precis Chem &

Mol Engn Feringa Nobel Prize Scientist Joint Res Ctr Sch Chem &

Mol Engn Key Lab Adv Mat 130 Meilong Rd Shanghai 200237 Peoples R China;

East China Univ Sci &

Technol Joint Int Res Lab Precis Chem &

Mol Engn Feringa Nobel Prize Scientist Joint Res Ctr Sch Chem &

Mol Engn Key Lab Adv Mat 130 Meilong Rd Shanghai 200237 Peoples R China;

East China Univ Sci &

Technol Joint Int Res Lab Precis Chem &

Mol Engn Feringa Nobel Prize Scientist Joint Res Ctr Sch Chem &

Mol Engn Key Lab Adv Mat 130 Meilong Rd Shanghai 200237 Peoples R China;

East China Univ Sci &

Technol Joint Int Res Lab Precis Chem &

Mol Engn Feringa Nobel Prize Scientist Joint Res Ctr Sch Chem &

Mol Engn Key Lab Adv Mat 130 Meilong Rd Shanghai 200237 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC-Au(i) complex [J] . Zhan Licheng, Zhang Gengtao, Wang Jiwei, RSC Advances . 2020,第58期

机译：基于四碳喹啉的手性卡贝蛋白前体和相关手性NHC-Au（i）复合物合成
2. Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex [J] . Licheng Zhan, Gengtao Zhang, Jiwei Wang, RSC Advances . 2020,第58期

机译：基于四碳喹啉的手性卡贝蛋白前体和相关手性NHC-Au（i）复合物合成
3. C-2-Symmetric Hindered "Sandwich" Chiral N-Heterocyclic Carbene Precursors and Their Transition Metal Complexes: Expedient Syntheses, Structural Authentication, and Catalytic Properties [J] . Liu Cong, Shen Hong-Qiang, Chen Mu-Wang, Organometallics . 2018,第21期

机译：C-2 - 对称阻碍“夹心”手性N-杂环卡链前体及其过渡金属配合物：有利合成，结构认证和催化性质
4. Enantioselective Synthesis of Various Planar-Chiral Metallocenes Catalyzed by Chiral Mo-or Ru-Carbene Complexes [C] . Masamichi Ogasawara, Susumu Watanabe, Kiyohiko Nakajima Symposium on Organometallic Chemistry . 2008

机译：手性Mo-或Ru- Carbene络合催化的各种平面手性茂金属的对映选择性合成
5. Synthesis and luminescence of organometallic complexes. Part I: Rhenium(I) carbonyl complexes and their ligands in anion recognition. Part II: Chiral ferrocenyl-substituted N-heterocyclic carbene ligands [D] . Odago, Maurice Otieno 2010

机译：有机金属配合物的合成和发光。第一部分：R（I）羰基配合物及其配体在阴离子识别中的作用。第二部分：手性二茂铁基取代的N-杂环卡宾配体
6. Potent Anticancer Activity with High Selectivity ofa Chiral Palladium N-Heterocyclic Carbene Complex [O] . Anuj Kumar, ∥, ⊥, 2017

机译：具有高选择性的强抗癌活性手性钯N-杂环碳配合物
7. Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex [O] . Licheng Zhan, Gengtao Zhang, Jiwei Wang, 2020

机译：基于四碳喹啉的手性卡贝蛋白前体和相关手性NHC-Au（i）复合物合成
8. Syntheses and Structures of New Pyridino-18-Crown-6 Ligands Containing TwoMethyl, Two t-Butyl or Two Allyl Substituents on Chiral Positions Next to the Pyridine Ring [R] . Habata, Y., Bradshaw, J. S., Young, J. J., 1996

机译：在pyridine环旁边的手性位置上含有两个甲基，两个叔丁基或两个烯丙基取代基的新吡啶基-18-冠-6配体的合成和结构

Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC-Au(i) complex

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