Exploring an anomaly: the synthesis of 7,7 '-diazaindirubin through a 7-azaindoxyl intermediate

Shriver James A.; Wang Katelyn R.; Patterson Andrew C.; DeYoung James R.; Lipsius Richard J.

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Exploring an anomaly: the synthesis of 7,7 '-diazaindirubin through a 7-azaindoxyl intermediate

机译：探索异常：通过7-氮杂氧基中间体合成7,7' -diazaindirubin

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Two independent methods generating 7-azaindoxyl as an intermediate verify that 7,7 '-diazaindirubin is formed exclusively over 7,7 '-diazaindigo. This contrasts with long-standing knowledge related to the reactivity of indoxyl, which proceedsviaa radical-initiated homodimerization process, leading to indigo. A series of experiments confirms 7-azaindoxyl as an intermediate with results suggesting a condensation pathway followed by oxidation.

机译：产生7-唑代氧基作为中间体的两个独立方法验证了7,7'-二Zaindirubin，专门超过7,7' -diazaindigo形成。这与与吲哚基的反应性相关的长期知识对比，该吲哚基的反应性，该方法是导致靛蓝。一系列实验证实了7-氮杂氧基作为中间体，其结果表明凝结途径随后是氧化。

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《RSC Advances》 |2020年第60期|共4页
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Shriver James A.; Wang Katelyn R.; Patterson Andrew C.; DeYoung James R.; Lipsius Richard J.;
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Cent Coll 812 Univ St Pella IA 50219 USA;

Cent Coll 812 Univ St Pella IA 50219 USA;

Cent Coll 812 Univ St Pella IA 50219 USA;

Cent Coll 812 Univ St Pella IA 50219 USA;

Cent Coll 812 Univ St Pella IA 50219 USA;

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正文语种 eng
中图分类化学;
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1. Exploring an anomaly: the synthesis of 7,7 '-diazaindirubin through a 7-azaindoxyl intermediate [J] . Shriver James A., Wang Katelyn R., Patterson Andrew C., RSC Advances . 2020,第60期

机译：探索异常：通过7-氮杂氧基中间体合成7,7' -diazaindirubin
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Exploring an anomaly: the synthesis of 7,7 '-diazaindirubin through a 7-azaindoxyl intermediate

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