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Enhanced photoelectrochemical activity of Co-doped beta-In2S3 nanoflakes as photoanodes for water splitting

机译:增强了共掺杂β-In2S3纳米薄片作为水分裂的光桥的光电化学活性

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摘要

This work is primarily focused on indium sulfide (beta-In2S3) and cobalt (Co)-doped beta-In2S3 nanoflakes as photoanodes for water oxidation. The incorporation of cobalt introduces new dopant energy levels increasing visible light absorption and leading to improved photo-activity. In addition, cobalt ion centers in beta-In2S3 act as potential catalytic sites to promote electro-activity. 5 mol% Co-doped beta-In2S3 nanoflakes when tested for photoelectrochemical water splitting exhibited a photocurrent density of 0.69 mA cm(-2) at 1.23 V, much higher than that of pure beta-In2S3.
机译:这项工作主要集中在硫化物(Beta-In2S3)和钴(Co) - 掺杂的β-In2S3纳米蛋糕作为水氧化。 钴的掺入引入了新的掺杂剂能级,增加了可见光吸收并导致改善的光活性。 此外,β-In2S3中的钴离子中心充当潜在的催化位点,以促进电活性。 当测试光电化学水分离时,5mol%的共掺杂β-In2S3纳米薄片在1.23V下表现出0.69 mA cm(-2)的光电流密度,远高于纯β-In2S3。

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  • 来源
    《RSC Advances》 |2019年第3期|共6页
  • 作者单位

    Indian Inst Technol Hyderabad Dept Chem Engn Sangareddy 502285 Telangana India;

    Indian Inst Technol Hyderabad Dept Chem Engn Sangareddy 502285 Telangana India;

    Indian Inst Technol Hyderabad Dept Chem Sangareddy 502285 Telangana India;

    Indian Inst Technol Hyderabad Dept Chem Engn Sangareddy 502285 Telangana India;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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