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High acidity cellulose sulfuric acid from sulfur trioxide: a highly efficient catalyst for the one step synthesis of xanthene and dihydroquinazolinone derivatives

机译:来自三氧化硫的高酸度纤维素硫酸:一种高效的催化剂,用于X吨和二氢喹唑啉酮衍生物的一步合成

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摘要

A cellulose sulfonate catalyst (HS-cellulose sulfonate) with high stability, excellent catalytic activity and high acidity value (about 1.55 mmol g(-1)) was successfully prepared by SO3 gas phase sulfonation. The basic morphology and nanostructure of the catalyst were determined by HRTEM, XRD, IR, TG, etc. In addition, the catalyst was applied to the catalytic reaction of a dihydroquinazolinone derivative and a xanthene compound, and very valuable results were obtained. The development and preparation of cellulose sulfonate catalysts provide a good approach for the development and application of cellulose, and also an important application of green organic catalytic synthesis methodology.
机译:通过SO 3气相磺化成功地制备了高稳定性,优异的催化活性和高酸度值(约1.55mmolg(-1))的纤维素磺酸酯(HS-纤维素磺酸盐)。 通过HRTEM,XRD,IR,Tg等测定催化剂的基本形态和纳米结构,另外,将催化剂施加到二氢喹唑啉酮衍生物和X吨化合物的催化反应中,得到非常有价值的结果。 磺酸纤维素催化剂的开发和制备提供了纤维素的开发和应用的良好方法,以及绿色有机催化合成方法的重要应用。

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    《RSC Advances》 |2019年第49期|共6页
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  • 正文语种 eng
  • 中图分类 化学;
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