Thermoregulated phase-separable rhodium nanoparticle catalyst for selective hydrogenation of alpha,beta-unsaturated aldehydes and ketones

Xue Xiuru; Niu Mingming; Xu Yicheng; Wang Yanhua

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Thermoregulated phase-separable rhodium nanoparticle catalyst for selective hydrogenation of alpha,beta-unsaturated aldehydes and ketones

机译：热调节相分离的铑纳米粒子催化剂，用于选择性氢化α，β不饱和醛和酮的选择性氢化

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Thermoregulated phase-separable Rh nanoparticles (abbreviated as TPS-Rh-nano) were found to be efficient catalysts for selective hydrogenation of C=C bonds in alpha,beta-unsaturated aldehydes and ketones with a selectivity of >99% at >99% conversion. More importantly, the catalyst could be easily separated by simple phase separation and reused directly eight times without evident loss in activity and selectivity.

机译：发现热调节相分离的RH纳米颗粒（缩写为TPS-RH-NANO）是为了有效催化剂，用于在α，β-不饱和醛和酮中选择性氢化C = C键，选择性> 99％的转化率> 99％。更重要的是，催化剂可以通过简单的相分离容易地分离，并直接重复用八次而无明显丧失活性和选择性。

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《RSC Advances》 |2017年第79期|共4页
作者
Xue Xiuru; Niu Mingming; Xu Yicheng; Wang Yanhua;
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Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Thermoregulated phase-separable rhodium nanoparticle catalyst for selective hydrogenation of alpha,beta-unsaturated aldehydes and ketones [J] . Xue Xiuru, Niu Mingming, Xu Yicheng, RSC Advances . 2017,第79期

机译：热调节相分离的铑纳米粒子催化剂，用于选择性氢化α，β不饱和醛和酮的选择性氢化
2. Selective Hydrogenation of alpha,beta-Unsaturated Aldehydes and Ketones using Novel Manganese Oxide and Platinum Supported on Manganese Oxide Octahedral Molecular Sieves as Catalysts [J] . ChemCatChem . 2013,第2期

机译：使用新的锰氧化物和铂金属氧化锰八面体分子筛作为催化剂的新型氧化锰和铂的选择性氢化α，β-不饱和醛和酮
3. Selective hydrogenation of alpha,beta-unsaturated ketone to alpha,beta-unsaturated alcohol on gold-supported iron oxide catalysts: Role of the support [J] . C.Milone, R.Ingoglia, L.Schipilliti, Journal of Catalysis . 2005,第1期

机译：在金负载的氧化铁催化剂上将α，β-不饱和酮选择性氢化为α，β-不饱和醇：载体的作用
4. Novel Manganese Oxide and Platinum/Manganese Oxide Octahedral Molecular Sieves Catalyst for Selective Hydrogenation of α,β-unsaturated Aldehydes and Ketones [C] . Haresh G. Manyar, Helen Daly, Helen Moor, 6th international conference on environmental catalysis : Abstract book . 2010

机译：新型氧化锰和铂/氧化锰八面体分子筛催化剂，用于α，β-不饱和醛和酮的选择性加氢
5. I. Chemoselective catalytic hydrogenation of alpha, beta-unsaturated aldehydes and ketones using soluble copper(I) hydrides II. Free radical alkylation of titanium(III) allyl and propargyl complexes. [D] . Chen, Jianxian. 1999

机译：I.使用可溶的氢化铜（I）对α，β-不饱和醛和酮进行化学选择性催化氢化。钛（III）烯丙基和炔丙基复合物的自由基烷基化。
6. Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones [O] . Hao-Yu Shen, Li-Yan Ying, Hai-Liang Jiang, 2007

机译：高效的铜-双异喹啉基催化剂用于将酒精选择性好氧氧化为醛和酮
7. Selective hydrogenation of α,βalpha,beta-unsaturated aldehydes towards clean synthesis over noble metal catalysts in mass transfer efficient three phase reactors [O] . Zhang Laiqi 1998

机译：α，βα，β-不饱和醛的选择性氢化在传质效率高的三相反应器中通过贵金属催化剂进行清洁合成
8. 9-Borabicyclo(3.3.1)nonane as a Highly Selective Reducing Agent for the Facile Conversion of alpha, beta-Unsaturated Aldehydes and Ketones to the Corresponding Allylic Alcohols in the Presence of Other Functional Groups. [R] . Krishnamurthy, S., Brown, H. C. 1975

机译：9-Borabicyclo（3.3.1）壬烷作为高选择性还原剂，用于在其他官能团存在下将α，β-不饱和醛和酮轻易转化为相应的烯丙醇。

Thermoregulated phase-separable rhodium nanoparticle catalyst for selective hydrogenation of alpha,beta-unsaturated aldehydes and ketones

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