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Enhanced capacities of carbon nanosheets derived from functionalized bacterial cellulose as anodes for sodium ion batteries

机译:增强碳纳米型衍生自官能化细菌纤维素作为钠离子电池阳极的碳纳米片的能力

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摘要

We studied carbon nanosheets prepared from bacterial cellulose (BC) and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidized-BC through carbonization at temperatures ranging from 900 to 1100 degrees C. Based on experimental results, we propose a comprehensive perspective of Na storage for BC based anode material. The pyrolysis TEMPO-oxidized BC delivers the highest capacity at annealing temperature of 1000 degrees C under different current densities, and displays excellent rate capability and cyclability. The superior electrochemical performance is attributed to the increasing interlayer distance, rich porous structure and oxygen-containing functional groups. The experimental studies reveal that the introduction of carboxyl is an effective strategy to enhance the specific capacity and cycling stability for Na-ion storage.
机译:我们研究了从细菌纤维素(BC)和2,2,6,6-四甲基哌啶-1-氧基(Tempo)氧化-BC的碳纳米片通过碳化在900至1100℃的温度范围内。基于实验结果,我们提出 基于BC的阳极材料NA存储的综合透视。 热解速度氧化BC在不同电流密度下,在1000摄氏度的退火温度下提供最高容量,并显示出优异的速率能力和可阻碍性。 卓越的电化学性能归因于中间距离增加,富孔结构和含氧官能团。 实验研究表明,羧基的引入是增强Na离子储存的特定容量和循环稳定性的有效策略。

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  • 来源
    《RSC Advances》 |2017年第79期|共7页
  • 作者单位

    Donghua Univ Coll Text Shanghai 201620 Peoples R China;

    Chinese Acad Sci Lanzhou Inst Chem Phys State Key Lab Solid Lubricat Lab Clean Energy Chem &

    Mat Lanzhou 730000 Gansu Peoples R China;

    Chinese Acad Sci Lanzhou Inst Chem Phys State Key Lab Solid Lubricat Lab Clean Energy Chem &

    Mat Lanzhou 730000 Gansu Peoples R China;

    Chinese Acad Sci Lanzhou Inst Chem Phys State Key Lab Solid Lubricat Lab Clean Energy Chem &

    Mat Lanzhou 730000 Gansu Peoples R China;

    Chinese Acad Sci Lanzhou Inst Chem Phys State Key Lab Solid Lubricat Lab Clean Energy Chem &

    Mat Lanzhou 730000 Gansu Peoples R China;

    Donghua Univ Coll Text Shanghai 201620 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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