Iron (III) trichloride-catalyzed one-pot three-component coupling of indoles and sodium nitrite: A convenient synthesis of 2,3'-bi(3H-indol)-3-one oximes

Qu H.; Qin W.; Chang Q.; Hu Q.; Liu L.

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Iron (III) trichloride-catalyzed one-pot three-component coupling of indoles and sodium nitrite: A convenient synthesis of 2,3'-bi(3H-indol)-3-one oximes

机译：三氯化铁（III）催化的吲哚与亚硝酸钠的一锅三组分偶联：2,3'-bi（3H-吲哚）-3-one肟的便捷合成

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A simple, convenient and efficient three-component coupling (TCC) reaction toward a variety of (E)-2,3'-bi(3H-indol)-3-one oxime derivatives has been developed. This transformation proceeds via an iron (III)-catalyzed tandem coupling reaction between indoles and sodium nitrite. This methodology provides an alternative approach for easy access of (E)-2,3'-bi(3H-indol)-3-one oximes in good to excellent yields at room temperature.

机译：已开发出一种针对各种（E）-2,3'-bi（3H-吲哚）-3-one肟衍生物的简单，便捷和高效的三组分偶联（TCC）反应。该转化通过吲哚和亚硝酸钠之间铁（III）催化的串联偶联反应进行。该方法学提供了另一种方法，可在室温下以良好或优异的收率轻松获得（E）-2,3'-bi（3H-吲哚）-3-one肟。

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《Current organic chemistry》 |2013年第7期|共7页
作者
Qu H.; Qin W.; Chang Q.; Hu Q.; Liu L.;
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正文语种 eng
中图分类有机化学;
关键词
Biindoles; Indoles; Iron (iii) trichloride; Tandem reactions; Three-component coupling reaction;

机译：双吲哚;吲哚;三氯化铁（iii）串联反应;三组分偶联反应;

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1. Iron (III) trichloride-catalyzed one-pot three-component coupling of indoles and sodium nitrite: A convenient synthesis of 2,3'-bi(3H-indol)-3-one oximes [J] . Qu H., Qin W., Chang Q., Current organic chemistry . 2013,第7期

机译：三氯化铁（III）催化的吲哚与亚硝酸钠的一锅三组分偶联：2,3'-bi（3H-吲哚）-3-one肟的便捷合成
2. Methylsulfonic acid adsorbed on silica gel as a solid acid for dimerization of indoles: A convenient synthesis of 2,3'-Bi(3 H -indol)-3-one oximes [J] . Chang Q., Qu H., Qin W., Synthetic Communications . 2013,第19a21期

机译：甲基磺酸作为固体酸吸附在硅胶上，用于吲哚的二聚：2,3'-Bi（3 H-吲哚）-3-one肟的简便合成
3. A new convenient four-component synthesis of 6-amino-2H,4H-pyrano[2,3-c]pyrazole-5-carbonitriles and one-pot synthesis of 6-amino-5-eyano-1,2-dihydrospiro-[(3H)-indole-3,4'-(4'H)-pyrano]2,3-c[pyrazol]-2-ones [J] . Yu. M. Litvinov, L. A. Rodinovskaya, A. M. Shestopalov Russian Chemical Bulletin . 2009,第11期

机译：一种新的方便的6-氨基-2H，4H-吡喃并[2,3-c]吡唑-5-腈的四组分合成方法和一锅合成6-氨基-5-乙氧基-1,2-二氢螺-[ （3H）-吲哚-3,4'-（4'H）-吡喃] 2,3-c [吡唑] -2-酮
4. Reactions of Disilyne with Nitrites: Synthesis and Structure of Bis(silylene-silylcyanide complex) and 1,4-diaza-2,3-disilabenzene [C] . Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi Symposium on Organometallic Chemistry . 2008

机译：DENIDENE与亚硝酸盐的反应：双（甲硅烷基甲硅烷基氰化物复合物）和1,4-diaza-2,3-二甲基苯的合成和结构
5. Synthesis of Iron-Cellulose Complex Using Sodium Nitrite and Iron Moiety for Fluoride Adsorption [D] . Aminy, Yasamen. 2021

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6. Three-Component One-Pot Synthesis of Highly FunctionalizedBis-Indole Derivatives [O] . Xue-Bing Chen, *, Sheng-Li Xiong, 2019

机译：高功能化三组分一锅法合成双吲哚衍生物
7. Three-Component One-Pot Synthesis of Highly Functionalized Bis-Indole Derivatives [O] . Xue-Bing Chen, Sheng-Li Xiong, Zhi-Xu Xie, 2019

机译：高官能化双吲哚衍生物的三组分一罐合成

Iron (III) trichloride-catalyzed one-pot three-component coupling of indoles and sodium nitrite: A convenient synthesis of 2,3'-bi(3H-indol)-3-one oximes

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