Recent advances in heterogeneous catalysts for the synthesis of imidazole derivatives

Nagaraju Kerru; Sandeep V. H. S. Bhaskaruni; Lalitha Gummidi; Surya Narayana Maddila; Suresh Maddila; Sreekantha B. Jonnalagadda

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Recent advances in heterogeneous catalysts for the synthesis of imidazole derivatives

机译：异质催化剂的最新进展，用于合成咪唑衍生物

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Among the bioactive heterocyclic frameworks, nitrogen containing multisubstituted imidazoles are versatile building blocks of many naturally occurring products. Imidazoles possess wide range of biological properties including anticancer, anti-inflammatory, antimicrobial, and antihypertensive activities with potential applications in other sectors. Multicomponent reactions in combination with heterogeneous catalysts and nanocomposites have contributed significantly to organic synthesis in general and imidazoles, in particular with high functional group tolerance. Owing to their tunable properties, lower operational cost, thermal stability, recyclability, and easily separation from products, heterogeneous catalysts and nanocomposites are integral part of numerous pharmaceutical, agrochemical, and industrial processes. There has been increased focus on the development of green and sustainable catalytic procedures for the building of novel and biologically potent imidazole conjugates. This article emphasizes the recent advances in recyclable catalysts and protocols, and their merits for the synthesis of diverse multisubstituted imidazole conjugates by one-pot reaction approach and the catalyst and reactant interactions.

机译：在生物活性杂环骨架中，含有多异取咪唑的氮是许多天然存在的产品的多功能构建块。 Imidazoles具有广泛的生物特性，包括抗癌，抗炎，抗微生物和抗高血压活动，以及其他部门的潜在应用。与异质催化剂和纳米复合材料组合的多组分反应对一般和咪唑的有机合成有显着贡献，特别是具有高官能团的耐受性。由于其可调性，较低的操作成本，热稳定性，可再循环性和易于与产物的分离，异构催化剂和纳米复合材料是无数药物，农业化学和工业过程的一部分。有于建立新型和生物学高效咪唑缀合物的绿色和可持续催化程序的开发的焦点。本文强调可再循环催化剂和方案的最近进展，以及通过单罐反应方法和催化剂和反应物相互作用合成各种多用户咪唑缀合物的优点。

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来源
《Synthetic Communications》 |2019年第20期|共23页
作者
Nagaraju Kerru; Sandeep V. H. S. Bhaskaruni; Lalitha Gummidi; Surya Narayana Maddila; Suresh Maddila; Sreekantha B. Jonnalagadda;
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作者单位

School of Chemistry and Physics University of KwaZulu-Natal Durban South Africa;

School of Chemistry and Physics University of KwaZulu-Natal Durban South Africa;

School of Chemistry and Physics University of KwaZulu-Natal Durban South Africa;

School of Chemistry and Physics University of KwaZulu-Natal Durban South Africa;

School of Chemistry and Physics University of KwaZulu-Natal Durban South Africa;

School of Chemistry and Physics University of KwaZulu-Natal Durban South Africa;

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正文语种 eng
中图分类有机化学;
关键词
Heterogeneous catalysis; multicomponent reactions; multisubstituted imidazoles; one-pot synthesis;

机译：异质催化;多组分反应;多用户的咪唑;单罐合成;

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专利

1. Recent advances in heterogeneous catalysts for the synthesis of imidazole derivatives [J] . Nagaraju Kerru, Sandeep V. H. S. Bhaskaruni, Lalitha Gummidi, Synthetic Communications . 2019,第17a20期

机译：异质催化剂的最新进展，用于合成咪唑衍生物
2. CuFe2O4 nanoparticles: an efficient heterogeneous magnetically separable catalyst for synthesis of some novel propynyl-1H-imidazoles derivatives [J] . El-Remaily Mahmoud Abd El Aleem Ali Ali, Abu-Dief Ahmed M. Tetrahedron . 2015,第17期

机译：CuFe2O4纳米颗粒：一种有效的非均相磁分离催化剂，用于合成某些新型丙炔基-1H-咪唑衍生物
3. Sulfated Tin Oxide: A Reusable and Highly Efficient Heterogeneous Catalyst for the Synthesis of 2,4,5-Triaryl-1H-imidazole Derivatives [J] . Satish A. Dake, Mahesh B. Khedkar, Ghanshyam S. Irmale, Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 2012,第10期

机译：硫酸锡：一种可重复使用的高效多相催化剂，用于合成2,4,5-三芳基-1H-咪唑衍生物
4. One-Pot Synthesis of Indole Derivatives Using Homogeneous and Polymer-Supported Heterogeneous Palladium Catalysts [C] . Ken Tsutsumi, Hayato Sakai, Tsumoru Morimoto Symposium on Organometallic Chemistry . 2006

机译：使用均相和聚合物负载的非均相钯催化剂单罐合成吲哚衍生物
5. CATALYTIC HYDROGENATION OF PINENE DERIVATIVES OVER HETEROGENEOUS PALLADIUM AND PLATINUM CATALYSTS. THE USE AND MECHANISM OF NMR-SHIFT REAGENTS IN STEREOCHEMICAL ELUCIDATIONS. [D] . BOYD, WALTER ALVIN. 1972

机译：ENE异构体钯和铂催化剂上衍生物的加氢催化。核磁共振移位试剂在立体化学电泳中的用途和机理。
6. Synthesis Characterization and Catalytic Properties of Magnetic Fe3O4@FU: A Heterogeneous Nanostructured Mesoporous Bio-Based Catalyst for the Synthesis of Imidazole Derivatives [O] . Maryam Banazadeh, Sara Amirnejat, Shahrzad Javanshir 2020

机译：磁Fe3O4 @Fu的合成表征和催化性能：一种用于合成咪唑衍生物的非均相纳米结构介孔生物基催化剂
7. Synthesis, Characterization, and Catalytic Properties of Magnetic Fe3O4@FU: A Heterogeneous Nanostructured Mesoporous Bio-Based Catalyst for the Synthesis of Imidazole Derivatives [O] . Maryam Banazadeh, Sara Amirnejat, Shahrzad Javanshir 2020

机译：磁Fe3O4 @Fu的合成，表征和催化性能：一种用于合成咪唑衍生物的非均相纳米结构介孔生物基催化剂

Recent advances in heterogeneous catalysts for the synthesis of imidazole derivatives

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