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Hetero-association models of non-covalent molecular complexation

机译:非共价分子络合的异质关联模型

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摘要

The present review discusses the current state-of-the-art in building models enabling the description of non-covalent equilibrium complexation of different types of molecules in solution, which results in the formation of supramolecular structures different in length and composition (hetero-association or supramolecular multicomponent co-polymerisation). The description is focused on standard physical and chemical quantities such as experimental observables and equilibrium parameters of interaction (equilibrium constants and concentrations). The major partial cases of the hetero-association models, such as finite and indefinite isodesmic and cooperative complexations, and Benesi-Hildebrand and Langmuir adsorption models are considered. Future challenges in the development of the hetero-association models are provided.
机译:本综述讨论了在建筑模型中的当前最先进的建筑模型,使得在溶液中的不同类型分子的非共价平衡络合的描述,这导致形成的长度和组成(异质结合)的超分子结构 或超分子的多组分共聚化)。 该描述专注于标准物理和化学量,例如实验性可观察和相互作用(平衡常数和浓度)的实验性可观察和平衡参数。 杂交关联模型的主要部分病例,例如有限和无限的体育和合作综合体,以及Benesi-Hildebrand和Langmuir吸附模型。 提供了异质协会模型的未来挑战。

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