Synthesis and characterization of a ruthenium complex with bis (diphenylphosphino)propane and thioether containing ONS donor ligand: Application in transfer hydrogenation of ketones

Biswas Sujan; Sarkar Deblina; Roy Puspendu; Mondal Tapan Kumar

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Synthesis and characterization of a ruthenium complex with bis (diphenylphosphino)propane and thioether containing ONS donor ligand: Application in transfer hydrogenation of ketones

机译：双（二苯基膦基）丙烷和含有ONS供体配体的钌络合物的合成与表征：在酮转移氢化中的应用

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The synthesis and characterization of a mixed ligand Ru(II) complex, [Ru(dppp)(L)CI] (1) (where, dppp = bis(diphenylphosphino) propane) is reported. The distorted octahedral geometry of the complex is confirmed by X-ray diffraction method. Cyclic voltammogram in CH3CN exhibits Ru(ID/Ru(III) quasireversible oxidation couple along with reversible azo-bond reductions peaks with reference to Ag/AgCI electrode. The efficiency of the complex towards the transfer hydrogenation of ketones in i-PrOH is examined and an excellent catalytic conversion (90-98%) is observed. The electronic structure and redox properties are well corroborated with the DFT calculations. (C) 2017 Elsevier Ltd. All rights reserved.

机译：报道了混合配体Ru（II）复合物的合成和表征，[Ru（DPPP）（L）C 1]（1）（其中，DPPP =双（二苯基膦基）丙烷）。通过X射线衍射法确认复合物的扭曲的八面体几何形状。 CH3CN中的循环伏安图展示Ru（ID / Ru（III）加速氧化耦合以及可逆偶氮键减少峰，参照Ag / Agci电极。检查了I-ProH中酮转移氢化的复合物的效率和观察到优异的催化转化（90-98％）。电子结构和氧化还原性能与DFT计算良好。（c）2017 Elsevier Ltd.保留所有权利。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2017年第2017期|共7页
作者
Biswas Sujan; Sarkar Deblina; Roy Puspendu; Mondal Tapan Kumar;
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作者单位

Jadavpur Univ Inorgan Chem Sect Dept Chem Kolkata 700032 India;

Jadavpur Univ Inorgan Chem Sect Dept Chem Kolkata 700032 India;

Jadavpur Univ Inorgan Chem Sect Dept Chem Kolkata 700032 India;

Jadavpur Univ Inorgan Chem Sect Dept Chem Kolkata 700032 India;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Ruthenium complex; Thioether ligand; Electrochemistry; Transfer hydrogenation of ketones; DFT calculation;

机译：钌络合物;硫醚配体;电化学;转移酮的氢化;DFT计算;

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1. Synthesis and characterization of a ruthenium complex with bis (diphenylphosphino)propane and thioether containing ONS donor ligand: Application in transfer hydrogenation of ketones [J] . Biswas Sujan, Sarkar Deblina, Roy Puspendu, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2017,第期

机译：双（二苯基膦基）丙烷和含有ONS供体配体的钌络合物的合成与表征：在酮转移氢化中的应用
2. Transfer hydrogenation of ketones catalyzed by complexes of ruthenium(II) with the heterotridentate [P,N,O] ligands (S)-2-[{2-(diphenylphosphanyebenzylidene}amino]propan-1-ol, (S)-2-[{2-(diphenylphosphanyl)benzyl}amino]propan-1-ol or the [P,N,S] ligand (S)-2-(dimethylamino)-1-(diphenylphosphino)-3-(methylthio)propane [J] . Obaid Abeer H., Stracey Nuru G., Incarvito Christopher D., Journal of Organometallic Chemistry . 2017,第期

机译：用钌（II）络合物催化的酮氢化与杂偶ideidate [p，n，O]配体（s）-2 - [{2-（二苯基磷胆亚苄基}氨基] propan-1-ol，（s）-2- [{2-（二苯基膦酰基）苄基}氨基]丙酮-1-醇或[P，N，S]配体（S）-2-（二甲基氨基）-1-（二苯基膦基）-3-（甲基硫基）丙烷
3. New active ruthenium(II) complexes based N3,N3 '-bis(diphenylphosphino)-2,2 '-bipyridine-3,3 '-diamine and P,P '-diphenylphosphinous acid-P,P '-[2,2 '-bipyridine]-3,3 '-diyl ester ligands for transfer hydrogenation of aromatic ketones by propan-2-ol [J] . Aydemir M, Baysal A, Meric N, Journal of Organometallic Chemistry . 2009,第16期

机译：基于N3，N3'-双（二苯基膦基）-2,2'-联吡啶-3,3'-二胺和P，P'-二苯基次膦酸-P，P'-[2,2'的新型活性钌（II）络合物-联吡啶] -3,3'-二烷基酯配体，用于通过丙-2-醇转移芳香酮
4. Effective Asymmetric Transfer Hydrogenation of Ketones Catalyzed by A New Chiral P-N-P Ligand-Ruthenium Complexes [C] . Yoji Oderaotoshi, Yuki Noguchi, Satoshi Minakata Symposium on Organometallic Chemistry . 2006

机译：新的手性P-N-P配体 - 钌配合物催化的酮催化的有效不对称转移氢化
5. Substitution chemistry of ruthenium clusters with the diphosphine ligands: 4,5-bis(diphenylphosphino)-4-cyclo-penten-1,3-dione (BPCD), (Z)-Ph(2)PCH=CHPPh(2) and 3,4-bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (BMF). [D] . Shen, Huanfeng. 1997

机译：具有二膦配体的钌簇的取代化学：4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（BPCD），（Z）-Ph（2）PCH = CHPPh（2）和3 ，4-双（二苯基膦基）-5-甲氧基-2（5H）-呋喃酮（BMF）。
6. Arene–Ruthenium(II) Complexes Containing 11H-Indeno12-bquinoxalin-11-oneDerivatives and Tryptanthrin-6-oxime: Synthesis CharacterizationCytotoxicity and Catalytic Transfer Hydrogenation of Aryl Ketones [O] . VladislavaV. Matveevskaya, Dmitry I. Pavlov, Taisiya S. Sukhikh, 2020

机译：含11H-茚并12-b喹喔啉-11-一的芳烃-钌（II）配合物衍生物和Tryptanthrin-6-肟：合成表征芳基酮的细胞毒性和催化转移加氢
7. Efficient Transfer Hydrogenation of Ketones Catalyzed by the Bis(isocyanide)-Ruthenium(II) Complexes trans, cis, cis-RuX2(CNR)2(dppf) (X = Cl, Br; dppf = 1, 1-Bis(diphenylphosphino)ferrocene): Isolation of Active Mono- and Dihydride Intermediates [O] . -1

机译：通过双（异氰化物）催化的酮的高效转移氢化 - 酮（II）络合物反式，顺式，顺式 - Rux2（CNR）2（DPPF）（X = Cl，Br; DPPF = 1,1-双（二苯基膦基）二茂铁）：活性单倍和二氢吡啶中间体分离

Synthesis and characterization of a ruthenium complex with bis (diphenylphosphino)propane and thioether containing ONS donor ligand: Application in transfer hydrogenation of ketones

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