Cobalt(II)-bis-(1,10-phenanthroline)-triphenylmethane dye complexes and their photo-sensitization properties in nano-porous photovoltaic devices

Jayaweera PM; Palayangoda SS; Tennakone K; Gamage RGCR

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Cobalt(II)-bis-(1,10-phenanthroline)-triphenylmethane dye complexes and their photo-sensitization properties in nano-porous photovoltaic devices

机译：钴（II）-双-（1,10-菲咯啉）-三苯甲烷染料配合物及其在纳米多孔光伏器件中的光敏特性

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摘要

Bromopyrogallol-red and pyrocatechol-violet, the two triphenylmethane-type ligands, can be readily complexed with [Co(1,10-phen)(2)](2+) moiety. The resulting complexes are capable of enhancing photovoltaic properties when compared with the corresponding ligands. Absorption and photocurrent action spectra suggest that a low-lying weak electronic charge transfer process, possibly a metal-to-ligand charge transfer (MLCT) process, is responsible for the enhancement of photovoltaic properties.

机译：两个三苯甲烷型配体溴邻苯三酚红和邻苯二酚紫可以很容易地与[Co（1,10-phen）（2）]（2+）部分络合。与相应的配体相比，所得复合物能够增强光伏性能。吸收光谱和光电流作用谱表明，低洼的弱电子电荷转移过程（可能是金属到配体的电荷转移（MLCT）过程）负责增强光伏性能。

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《Current Science: A Fortnightly Journal of Research》 |2002年第11期|共5页
作者
Jayaweera PM; Palayangoda SS; Tennakone K; Gamage RGCR;
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原文格式 PDF
正文语种 eng
中图分类自然科学现状及发展;
关键词
Tio2;

机译：二氧化钛;

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1. Cobalt(II)-bis-(1,10-phenanthroline)-triphenylmethane dye complexes and their photo-sensitization properties in nano-porous photovoltaic devices [J] . Jayaweera PM, Palayangoda SS, Tennakone K, Current Science: A Fortnightly Journal of Research . 2002,第11期

机译：钴（II）-双-（1,10-菲咯啉）-三苯甲烷染料配合物及其在纳米多孔光伏器件中的光敏特性
2. Synthesis, characterization and antimicrobial properties of cobalt(II) and cobalt(III) complexes derived from 1,10-phenanthroline with nitrate and azide co-ligands [J] . Djuikom Sado Yanick Ga?lle, Divine Mbom Yufanyi, Rajamony Jagan, Cogent Chemistry . 2016,第1期

机译：1,10-菲咯啉与硝酸盐和叠氮化物共配体衍生的钴（II）和钴（III）配合物的合成，表征和抗菌性能
3. Synthesis, characterization and antimicrobial properties of cobalt(II) and cobalt(III) complexes derived from 1,10-phenanthroline with nitrate and azide co-ligands [J] . Djuikom Sado Yanick Ga?lle, Divine Mbom Yufanyi, Rajamony Jagan, Cogent Chemistry . 2016,第1期

机译：1,10-菲咯啉与硝酸盐和叠氮化物共配体衍生的钴（II）和钴（III）配合物的合成，表征和抗菌性能
4. The Effect of 1,10-Phenanthroline on the Luminescent Properties of Eu(III) and Tb (III) Complexes with 2-Acetylnaphthol-hydrazinehydrate [C] . Yi-Min Feng International Conference on Material Science, Environmental Science and Computer Science . 2011

机译：1,10菲咯啉对欧盟（III）和Tb（III）复合物的升温性能的影响，具有2-乙酰萘酚 - 肼水合物
5. Optimization and application of photoluminescence-following electron-transfer with tris(tetramethyl-1,10-phenanthroline) Os/Ru(III) complexes and Fenton based chemiluminescence detection of NSAIDs and dopamine in biological samples. [D] . Patel, Mohit Pratish. 2016

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6. Dichlorido[N′-(3,5-dichloro-2-hydroxybenzylidene)pyridine-4-carbohydrazide-κN](1,10-phenanthroline-κ2N,N′)cobalt(II) methanol monosolvate [O] . Yuan Wang, Zheng Liu, Baoyu Liu 2016

机译：二氯基[N'-（（3,5-二氯-2-羟基苄叉叉基）吡啶-4-碳酰肼-κN]（1,10-菲咯啉-κ2N，N'）钴（II）甲醇单溶剂化物
7. A double salt of iodobismuthate: cis-aquaiodidobis(1,10-phenanthroline)cobalt(II) tris(1,10-phenanthroline)cobalt(II) trans-hexa-μ2-iodido-hexaiodidotribismuthate(III) [O] . Chen, Jiongke, Chai, Wenxiang, Song, Li, 2011

机译：碘代双杂酸酯的复盐：顺式-水碘代双（1,10-菲咯啉）钴（II）三（1,10-菲咯啉）钴（II）反式-μ-μ2-碘代-六碘代双核铋（III）

Cobalt(II)-bis-(1,10-phenanthroline)-triphenylmethane dye complexes and their photo-sensitization properties in nano-porous photovoltaic devices

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