Formation and identification of borane radical anions isolated in solid argon

Lin Meng-Yeh; Huang Tzu-Ping; Chin Chih-Hao; Wu Yu-Jong

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Formation and identification of borane radical anions isolated in solid argon

机译：固体氩水隔离的硼烷自由基阴离子的形成与鉴定

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The infrared (IR) spectrum of borane(3) anions (BH3-) isolated in solid Ar was recorded; two vibrational modes were observed at 2259.4 and 606.6 cm(-1), which were assigned to the BH2 stretching (nu(3)) and out-of-plane large-amplitude (nu(2)) modes, respectively. These anions were produced by the electron bombardment of an Ar matrix sample containing a small proportion of B2H6 and H-2 during matrix deposition or by the photolysis of single-bridged-B2H5 fi in an Ar matrix with the selected ultraviolet light. The band positions, relative intensity ratios, isotopic splitting pattern, and isotopic shift ratios of the observed IR features of BH3- are generally in good agreement with those predicted by the B2PLYP/aug-cc-pVTZ method.

机译：记录固体AR中分离的硼烷（3）个阴离子（BH3-）的红外（IR）光谱; 在2259.4和606.6cm（-1）下观察到两种振动模式，分别分配给BH2拉伸（NU（3））和外平面外部大幅度（NU（2））模式。这些阴离子由含有小比例的B2H6和H-2期间的AR基质样品的电子轰击，或者通过用所选紫外光光解体在AR基质中光解。 BH3的观察IR特征的带位置，相对强度比，同位素分裂图谱和同位素偏移比通常与由B2PLYP / AUG-CC-PVTZ方法预测的那些吻合良好。

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《The Journal of Chemical Physics》 |2018年第7期|共5页
作者
Lin Meng-Yeh; Huang Tzu-Ping; Chin Chih-Hao; Wu Yu-Jong;
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Natl Synchrotron Radiat Res Ctr 101 Hsin Ann Rd Hsinchu Sci Pk Hsinchu 30076 Taiwan;

Natl Synchrotron Radiat Res Ctr 101 Hsin Ann Rd Hsinchu Sci Pk Hsinchu 30076 Taiwan;

Natl Synchrotron Radiat Res Ctr 101 Hsin Ann Rd Hsinchu Sci Pk Hsinchu 30076 Taiwan;

Natl Synchrotron Radiat Res Ctr 101 Hsin Ann Rd Hsinchu Sci Pk Hsinchu 30076 Taiwan;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Formation and identification of borane radical anions isolated in solid argon [J] . Lin Meng-Yeh, Huang Tzu-Ping, Chin Chih-Hao, The Journal of Chemical Physics . 2018,第7期

机译：固体氩水隔离的硼烷自由基阴离子的形成与鉴定
2. Photochemical Formation and Reaction of Radical Pairs from NH_3-F_2 Complexes Isolated in Solid Argon [J] . Alexander V. Akimov, Ilia U. Goldschleger, Eugenii Ya. Misochko, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第42期

机译：固态氩中分离的NH_3-F_2配合物的自由基对的光化学形成和反应
3. Photochemistry and infrared spectrum of single-bridged diborane(5) anion isolated in solid argon [J] . Liu Meng-Chen, Chen Hui-Fen, Huang Wei-Jie, The Journal of Chemical Physics . 2016,第7期

机译：固氩中分离的单桥联乙硼烷（5）阴离子的光化学和红外光谱
4. Formation of Gas Phase Silver Anions and Silver-Iodide Radical Anions by Laser Ablation [C] . Timothy J. Dunne, Athula B. Attygalle ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：通过激光烧蚀形成气相银阴离子和银碘化物的阴离子
5. Synthesis and ligand substitution in polyhedral borane anions and transition metal complexes of heteroatom borane cages. [D] . Jasper, Stephen Alan, Jr. 1995

机译：多面体硼烷阴离子和杂原子硼烷笼的过渡金属络合物中的合成和配体取代。
6. Identification of a Simplest Hypervalent Hydrogen Fluoride Anion in Solid Argon [O] . Meng-Chen Liu, Hui-Fen Chen, Chih-Hao Chin, -1

机译：固态氩中最简单的高价氟化氢阴离子的鉴定
7. Infrared Spectra of the 1Methylvinoxide Radical and Anion Isolated in Solid Argon [O] . -1

机译：在固体氩中分离的1methylvinoxide自由基的红外光谱和阴离子
8. Identification and Condensation of Cyclic C6 and Cyclic C8 in Solid Argon Characterization of Matrix Isolated BjCn-j J=0, 1, 2,: n=3-11 in Solid Argon. [R] . Larson, C. W. 1999

机译：固体氩气中固体氩气中循环C6和环状C8的识别和凝聚BjCn-j J = 0,1,2，：n = 3-11在固体氩气中的表征。

Formation and identification of borane radical anions isolated in solid argon

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