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Communication: Multi-mass velocity map imaging study of a ultraviolet photodissociation of dimethyl sulfide using single photon ionization and a PImMS2 sensor

机译:通信:使用单光子电离和PIMMS2传感器的二甲基硫醚紫外线光积极的多质量速度映射研究

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摘要

This study of the photodissociation of dimethyl sulfide at lambda = 227.5 nm demonstrates the opportunities (and some of the challenges) of product detection using vacuum ultraviolet photoionization combined with recently developed multi-mass imaging methods. The capability of imaging different charged products simultaneously allows determination of the primary fragmentation dynamics through, for example, product fragment momentum and angular distribution matching and reveals potential complications from dissociative ionization, product alignment-dependent photoionization probabilities, and the effects of space charging. Published by AIP Publishing.
机译:该研究在Lambda = 227.5nm处的二甲基硫化物的光沉积证明了使用真空紫外线光化结合最近开发的多重成像方法的产品检测的机会(和一些挑战)。 同时成像不同的带电产品的能力允许通过例如产品片段动量和角度分布匹配来确定主要碎片动态,并揭示来自离灭电离,产品对准的光相概率的潜在并发症,以及空间充电的影响。 通过AIP发布发布。

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