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首页> 外文期刊>The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical >Relationship between Structure and Fluctuations of Lipid Nonlamellar Phases Deposited at the Solid-Liquid Interface
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Relationship between Structure and Fluctuations of Lipid Nonlamellar Phases Deposited at the Solid-Liquid Interface

机译:固液界面沉积脂质非混凝脉相的结构与波动的关系

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摘要

The structure and dynamics of nanostructure films formed by mixtures of soy phosphatidylcholine and glycerol dioleate at the silicon aqueous interface were studied by grazing incidence neutron spin echo spectroscopy (GINSES), specular and off-specular neutron, reflectometry, and small-angle X-ray diffraction. Reverse hexagonal (Hr) and micellar cubic phase (Fd3m) layers at: the solid liquid interface have been identified with neutron reflectometry measurements. A preferred orientation of the liquid crystalline (LC) domains was observed only for the anisotropic,H-II phase. The size of the LC domains was found to be about 1 micrometer as estimated from the width of the diffraction peaks. GINSES revealed that the cubic phase forms rather rigid films. In comparison, the HE film was more flexible, appearing as a modified undulation spectrum of the cylinders due to the interaction with the substrate.
机译:通过放牧入射中子旋转回波光谱谱(镜面和折射中子,反射测定测量和小角X射线,研究了通过硅水性界面的混合物形成的纳米结构膜的结构和动力学。 衍射。 反向六方(HR)和胶束立方相(FD3M)层:已经用中子反射测量测量鉴定了固体液体界面。 仅针对各向异性H-II期观察液晶(LC)结构域的优选取向。 从衍射峰的宽度估计,发现LC结构域的尺寸为约1微米。 胶林透露,立方相形成相当刚性薄膜。 相比之下,由于与基板的相互作用,他膜更加灵活,作为气缸的改进的下降谱。

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