Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

机译：凝固金属三（二烷基氨基）酰亚胺磷烷配合物作为铈配合物的透射基试剂

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We report the synthesis of tetrameric Cu(I) and Ag(I) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip)(3)](1-) and [NP(1,2-bis-Bu-t-diamidoethane)(NEt2)](1-) ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.

机译：我们报告了由Tris（哌啶基）酰亚胺磷烷[NP（PIP）（3）]（1-）和[NP（1,2-BIS-BU-）负载的四聚体Cu（I）和Ag（I）的聚络合物的合成 T-二胺乙烷）（NET2）]（1-）配体。这些配合物证明了酰亚胺磷素配体与氧化盐的氧化还原稳定性，并且银络合物又可以作为氧化透射化试剂，用于分离来自铈金属或三价铈前体的四价铈复合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2020年第17期|共4页
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正文语种 eng
中图分类化学;无机化学;
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1. Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第17期

机译：凝固金属三（二烷基氨基）酰亚胺磷烷配合物作为铈配合物的透射基试剂
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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

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