[4+2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategy

Begum Imtiaz; Kalisch Tim; Schnakenburg Gregor; Kelemen Zsolt; Nyulaszi Laszlo; Streubel Rainer

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[4+2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategy

机译：[4 + 2] -cycloaddition的噻唑基三环素1,4-二膦碱和一种新的易1,4-二膦保护脱保护策略

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Diels-Alder-reactions of a thiazol-2-thione-based, tricyclic 1,4-di-phosphinine were investigated, showing that the central aromatic It-system can react with various dienophiles. The reaction with 4-phenyl-1,2,4-triazoline-3,5-dione was special as the product revealed a remarkable sensitivity towards light, thus enabling the photochemical deprotection of the tricyclic 1,4-diphosphinine.

机译：研究了基于噻唑-2-尖端的三环1,4-二膦素的Diels-酰胺反应，表明中央芳族IT系统可以与各种辅酶素反应。与4-苯基-1,2,4-三唑啉-3,5-二酮的反应特殊，因为产品揭示了对光的显着敏感性，因此能够使三环1,4-二磷素的光化学脱保护。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2020年第36期|共4页
作者
Begum Imtiaz; Kalisch Tim; Schnakenburg Gregor; Kelemen Zsolt; Nyulaszi Laszlo; Streubel Rainer;
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作者单位

Rhein Friedrich Wilhelms Univ Inst Anorgan Chem Gerhard Domagk Str 1 D-53121 Bonn Germany;

Rhein Friedrich Wilhelms Univ Inst Anorgan Chem Gerhard Domagk Str 1 D-53121 Bonn Germany;

Rhein Friedrich Wilhelms Univ Inst Anorgan Chem Gerhard Domagk Str 1 D-53121 Bonn Germany;

Budapest Univ Technol &

Econ Dept Inorgan &

Analyt Chem Szt Gellert Ter 4 H-1111 Budapest Hungary;

Budapest Univ Technol &

Econ Dept Inorgan &

Analyt Chem Szt Gellert Ter 4 H-1111 Budapest Hungary;

Rhein Friedrich Wilhelms Univ Inst Anorgan Chem Gerhard Domagk Str 1 D-53121 Bonn Germany;

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正文语种 eng
中图分类化学;无机化学;
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1. [4+2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategy [J] . Begum Imtiaz, Kalisch Tim, Schnakenburg Gregor, Dalton transactions: An international journal of inorganic chemistry . 2020,第36期

机译：[4 + 2] -cycloaddition的噻唑基三环素1,4-二膦碱和一种新的易1,4-二膦保护脱保护策略
2. 7-Metalla-1,4-diphosphanorbornadienes: cycloaddition of monovalent group 13 NacNac complexes to a stable 1,4-diphosphinine [J] . Koner Abhishek, Gabidullin Bulat M., Kelemen Zsolt, Dalton transactions: An international journal of inorganic chemistry . 2019,第23期

机译：7-Metalla-1,4-二磷血砍刀：单价基团的环形加成13个NaCnAc复合物，稳定1,4-二磷氨基
3. 1,4-Dihydro-1λ~5,4λ~5-[1,4|diphosphinine und ein 1,4-Dihydro-1λ~5,4λ~3-[l,4]diphosphinin [J] . Klaus Bieger, Gernot Heckmann, Ekkehard Fluck, Zeitschrift fur Anorganische und Allgemeine Chemie . 1995,第12期

机译：1,4-二氢-1λ〜5,4λ〜5- [1,4 | diphosphinine和ein 1,4-二氢-1λ〜5,4λ〜3- [l，4]二膦
4. Preparation of new polyols based on Cis-1,4-polyisoprene by using 1,3-dipolar cycloaddition [C] . Ekasit ANANCHAROENWONG, Jean-Francois PILARD, Irene CAMPISTRON Asia Pacific Rubber Conference . 2014

机译：使用1,3-偶极环加入的基于CIS-1,4-聚异戊二烯的新多元醇的制备
5. An exploration of the cycloaddition and oxidative dehydrogenation chemistry of SNS+ with 1,4-quinone derivatives and characterization of the corresponding hybrid quinone-thiazyl cations and radicals. [D] . Mailman, Aaron. 2011

机译：探索具有1，4-醌衍生物的SNS +的环加成和氧化脱氢化学，以及相应杂化醌-噻唑基阳离子和自由基的表征。
6. A New Synthesis Strategy on Styrene-Butadiene Di-Block Copolymer Containing High cis-1,4 Unit Via Transfer of Anionic to Coordination Polymerization [O] . Jie Liu, Xin Min, Xiuzhong Zhu, 2018

机译：阴离子转移到配位聚合制备高顺式1,4单元苯乙烯-丁二烯二嵌段共聚物的合成新策略
7. Expanding the chemistry of ring-fused 1,4-diphosphinines by stable mono anion formation [O] . Imtiaz Begum, Gregor Schnakenburg, Zsolt Kelemen, 2018

机译：通过稳定的单阴离子形成膨胀环熔1,4-二磷碱的化学性质

[4+2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategy

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