Visible-light-driven hydrogen evolution using a polyoxometalate-based copper molecular catalyst

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Visible-light-driven hydrogen evolution using a polyoxometalate-based copper molecular catalyst

机译：使用聚氧酸盐基铜分子催化剂的可见光驱动的氢气进化

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Polyoxometalate-based copper clusters as promising hydrogen evolution catalysts are rarely reported. Here, [Cu-5(OH)(4)(H2O)(2)(A-alpha-SiW9O33)(2)](10-) (1) was tested as an effective molecular catalyst for visible-light-driven H-2 evolution. A high turnover number (TON) of 718.9 was achieved in the photocatalytic reaction. Many stability experiments showed that compound 1 could maintain its structure intact during the photocatalytic process.

机译：报道了作为有前途的氢进化催化剂的聚杂象晶型铜簇。这里，测试[Cu-5（OH）（4）（4）（2）（2）（A-α-SiW9O3）（2）]（10-）（10-）（10-）（1）作为可见光驱动的H的有效分子催化剂 -2进化。在光催化反应中实现了718.9的高端数（吨）。许多稳定性实验表明，化合物1可以在光催化过程中保持其结构完整。

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《Dalton transactions: An international journal of inorganic chemistry》 |2020年第11期|共6页
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正文语种 eng
中图分类化学;无机化学;
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1. Visible-light-driven hydrogen evolution using a polyoxometalate-based copper molecular catalyst [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第11期

机译：使用聚氧酸盐基铜分子催化剂的可见光驱动的氢气进化
2. A highly active cocatalyst-free semiconductor photocatalyst for visible-light-driven hydrogen evolution: synergistic effect of surface defects and spatial bandgap engineering [J] . Yu Guiyang, Zhang Wenxiang, Sun Yanjun, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2016,第36期

机译：用于可见光驱动的氢气释放的高活性无助催化剂半导体光催化剂：表面缺陷和空间带隙工程的协同效应
3. Cadmium Sulfide and Nickel Synergetic Co-catalysts Supported on Graphitic Carbon Nitride for Visible-Light-Driven Photocatalytic Hydrogen Evolution [J] . Xinzheng Yue, Shasha Yi, Runwei Wang, Scientific reports. . 2016,第1期

机译：石墨化氮化碳上负载的硫化镉和镍协同助催化剂，用于可见光驱动的光催化氢生成
4. Mo Thio and Oxo-Thio Molecular Complexes As Water-Soluble Self-Healing Catalysts for Photocatalytic Hydrogen Evolution on 2D Materials [C] . Pierre-Louis Taberna, Juliana Barros Barbosa, Jean-Yves Chane Ching, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：Mo Thio和Oxo-Thio分子复合物作为用于光催化氢进化的水溶性自愈催化剂在2D材料上
5. Molecular level interactions in bimetallic catalysts: A comprehensive study of factors critical for hydrogenation over copper-ruthenium/aluminum oxide. [D] . Palmieri, Michael Joseph, Jr. 1995

机译：双金属催化剂中的分子级相互作用：对铜-钌/氧化铝上加氢关键因素的综合研究。
6. Cadmium Sulfide and Nickel Synergetic Co-catalysts Supported on Graphitic Carbon Nitride for Visible-Light-Driven Photocatalytic Hydrogen Evolution [O] . Xinzheng Yue, Shasha Yi, Runwei Wang, -1

机译：石墨化氮化碳上负载的硫化镉和镍协同助催化剂用于可见光驱动的光催化氢生成
7. Research advances of light-driven hydrogen evolution using polyoxometalate-based catalysts [O] . Mo Zhang, Huijie Li, Junhao Zhang, 2021

机译：采用聚氧酸盐酸盐催化剂的光驱动氢气进化的研究进展

Visible-light-driven hydrogen evolution using a polyoxometalate-based copper molecular catalyst

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